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Self-healing materials have recently become more popular due to their capability to autonomously and autogenously repair the damage in cementitious materials. The concept of self-healing gives the damaged material the ability to recover its stiffness. This gives a difference in comparing with a material that is not subjected to healing. Once this material is damaged, it cannot sustain loading due to the stiffness degradation. Numerical modeling of self-healing materials is still in its infancy. Multiple experimental researches were conducted in literature to describe the behavior of self-healing of cementitious materials. However, few numerical investigations were undertaken.
The thesis presents an analytical framework of self-healing and super healing materials based on continuum damage-healing mechanics. Through this framework, we aim to describe the recovery and strengthening of material stiffness and strength. A simple damage healing law is proposed and applied on concrete material. The proposed damage-healing law is based on a new time-dependent healing variable. The damage-healing model is applied on isotropic concrete material at the macroscale under tensile load. Both autonomous and autogenous self-healing mechanisms are simulated under different loading conditions. These two mechanisms are denoted in the present work by coupled and uncoupled self-healing mechanisms, respectively. We assume in the coupled self-healing that the healing occurs at the same time with damage evolution, while we assume in the uncoupled self-healing that the healing occurs when the material is deformed and subjected to a rest period (damage is constant). In order to describe both coupled and uncoupled healing mechanisms, a one-dimensional element is subjected to different types of loading history.
In the same context, derivation of nonlinear self-healing theory is given, and comparison of linear and nonlinear damage-healing models is carried out using both coupled and uncoupled self-healing mechanisms. The nonlinear healing theory includes generalized nonlinear and quadratic healing models. The healing efficiency is studied by varying the values of the healing rest period and the parameter describing the material characteristics. In addition, theoretical formulation of different self-healing variables is presented for both isotropic and anisotropic maerials. The healing variables are defined based on the recovery in elastic modulus, shear modulus, Poisson's ratio, and bulk modulus. The evolution of the healing variable calculated based on cross-section as function of the healing variable calculated based on elastic stiffness is presented in both hypotheses of elastic strain equivalence and elastic energy equivalence. The components of the fourth-rank healing tensor are also obtained in the case of isotropic elasticity, plane stress and plane strain.
Recent research revealed that self-healing presents a crucial solution also for the strengthening of the materials. This new concept has been termed ``Super Healing``. Once the stiffness of the material is recovered, further healing can result as a strengthening material. In the present thesis, new theory of super healing materials is defined in isotropic and anisotropic cases using sound mathematical and mechanical principles which are applied in linear and nonlinear super healing theories. Additionally, the link of the proposed theory with the theory of undamageable materials is outlined. In order to describe the super healing efficiency in linear and nonlinear theories, the ratio of effective stress to nominal stress is calculated as function of the super healing variable. In addition, the hypotheses of elastic strain and elastic energy equivalence are applied. In the same context, new super healing matrix in plane strain is proposed based on continuum damage-healing mechanics.
In the present work, we also focus on numerical modeling of impact behavior of reinforced concrete slabs using the commercial finite element package Abaqus/Explicit. Plain and reinforced concrete slabs of unconfined compressive strength 41 MPa are simulated under impact of ogive-nosed hard projectile. The constitutive material modeling of the concrete and steel reinforcement bars is performed using the Johnson-Holmquist-2 damage and the Johnson-Cook plasticity material models, respectively. Damage diameters and residual velocities obtained by the numerical model are compared with the experimental results and effect of steel reinforcement and projectile diameter is studied.
Superplasticizers are utilized both to improve the fluidity during the placement and to reduce the water content of concretes. Both effects have also an impact on the properties of the hardened concrete. As a side effect the presence of superplasticizers affects the strength development of concretes that is strongly retarded. This may lead to an ecomomical drawback of the concrete manufacturing. The present work is aimed at gaining insights on the causes of the retarding effect of superplasticizers on the hydration of Portland cement. In order to simplify the complex interactions occurring during the hydration of Portland cement the majority of the work focuses on the interaction of superplasticizer and tricalcium silicate (Ca3SiO5 or C3S, the main compound of Portland cement clinker). The tests are performed in three main parts accompanied by methods as for example isothermal conduction calorimetry, electrical conductivity, Electron Microscopy, ICP-OES, TOC, as well as Analytical Ultracentrifugation.
In the first main part and based on the interaction of cations and anionic charges of polymers, the interactions between calcium ions and superplasticizers are investigated. As a main effect calcium ions are complexed by the functional groups of the polymers (carboxy, sulfonic). Calcium ions may be both dissolved in the aqueous phase and a constitute of particle interfaces. Besides these effects it is furthermore shown that superplasticizers induce the formation of nanoscaled particles which are dispersed in the aqueous phase (cluster formation). Analogous to recent findings in the field of biomineralization, it is reasonable to assume that these nanoparticles influence the crystal growth by their assembly process.
Based on the assumption that superplasticizers hinder either or both dissolution and precipitation and by that retard the cement hydration, the impact on separate reactions is investigated. On experiments that address the solubility of C-S-H phases and portlandite, it is shown that complexation of calcium ions in the aqueous phase by functional groups of polymers increases the solubility of portlandite. Contrary, in case of C-S-H solubility the complexation of calcium ions in solution leads to decrease of the calcium ion concentration in the aqueous phase. These effects are explained by differences in adsorption of polymers on C-S-H phases and portlandite. It is proposed that adsorption is stronger on C-S-H phases compared to portlandite due to the increased specific surface area of C-S-H phases. Following that, it is claimed that before polymers are able to adsorb on C-S-H phases the functional groups must be screened by calcium ions in the aqueous phase. It is further shown that data regarding the impact of superplasticizers on the unconstrained dissolution rate of C3S does not provide a clear relation to the overall retarding effect occurring during the hydration of C3S. Both increased and decreased dissolution rate with respect to the reference sample are detected. If the complexation capability of the superplasticizers is considered then also a reduced dissolution rate of C3S is determined. Despite the fact that the global hydration process is accelerated, the addition of calcite leads to a slower dissolution rate. Thus, a hindered unconstrained dissolution of C3S as possibly cause for the retarding effect still remains open for discussion. In the last section of this part, the pure crystallization of hydrate phases (C-S-H phases, portlandite) is fathomed. Results clearly show that superplasticizers prolong the induction time and modify the rate of crystal growth during pure crystallization in particular due to the complexation of ions in solution. But this effect is insufficient to account for the overall retarding effect. Further important factors are the blocking of crystal growth faces by adsorbed polymers and the dispersion of nanoscaled particles which hinders their agglomeration in order to build up crystals.
In the last main part of the work, the previously gathered results are utilized in order to investigate hydration kinetics. During hydration, dissolution and precipitation occur in parallel. Thereby, special attention is laid on the ion composition of the aqueous phase of C3S pastes and suspensions in order to determine the rate limiting step. All in all it is concluded that the retarding effect of superplasticizers on the hydration of tricalcium silicate is based on the retardation of crystallization of hydrate phases (C-S-H phases and portlandite). Thereby, the two effects complexation of calcium ions on surfaces and stabilization of nanoscaled particles are of major importance. These mechanisms may partly be compensated by template performance and increase in solubility by complexation of ions in solution. The decreased dissolution rate of C3S by the presence of superplasticizers during the in parallel occuring hydration process can only be assessed indirectly by means of the development of the ion concentrations in the aqueous phase (reaction path). Whether this observation is the cause or the consequence within the dissolution-precipitation process and therefore accounts for the retarding effect remains a topic for further investigations.
Besides these results it is shown that superplasticizers can be associated chemically with inhibitors because they reduce the frequency factor to end the induction period. Because the activation energy is widely unaffected it is shown that the basic reaction mechanism sustain. Furthermore, a method was developed which permits for the first time the determination of ion concentrations in the aqueous phase of C3S pastes in-situ. It is shown that during the C3S hydration the ion concentration in the aqueous phase is developed correspondingly to the heat release rate (calorimetry). The method permits the differentiation of the acceleration period in three stages. It is emphasized that crystallization of the product phases of C3S hydration, namely C-S-H phases and portlandite, are responsible for the end of the induction period.
In recent years, the discussion of digitalization has arrived in the media, at conferences, and in committees of the construction and real estate industry. While some areas are producing innovations and some contributors can be described as pioneers, other topics still show deficits with regard to digital transformation. The building permit process can also be counted in this category. Regardless of how architects and engineers in planning offices rely on innovative methods, building documents have so far remained in paper form in too many cases, or are printed out after electronic submission to the authority. Existing resources – for example in the form of a building information model, which could provide support in the building permit process – are not being taken advantage of. In order to use digital tools to support decision-making by the building permit authorities, it is necessary to understand the current situation and to question conditions before pursuing the overall automation of internal authority processes as the sole solution.
With a substantive-organizational consideration of the relevant areas that influence building permit determination, an improvement of the building permit procedure within authorities is proposed. Complex areas – such as legal situations, the use of technology, as well as the subjective alternative action – are determined and structured. With the development of a model for the determination of building permitability, both an understanding of influencing factors is conveyed and an increase in transparency for all parties involved is created.
In addition to an international literature review, an empirical study served as the research method. The empirical study was conducted in the form of qualitative expert interviews in order to determine the current state in the field of building permit procedures. The collected data material was processed and subsequently subjected to a software-supported content analysis. The results were processed, in combination with findings from the literature review, in various analyses to form the basis for a proposed model.
The result of the study is a decision model that closes the gap between the current processes within the building authorities and an overall automation of the building permit review process. The model offers support to examiners and applicants in determining building permit eligibility, through its process-oriented structuring of decision-relevant facts. The theoretical model could be transferred into practice in the form of a web application.
The capitalization of ‘certified’ sustainable building sector will be investigated over the power theory of value approach of Jonathan Nitzan and Shimshon Bichler. The study will be initiated by questioning why the environment problems are one of the first items on the agenda and by sharing the ideas of scholars who approaches the subject skeptically, because the predominant literature underlying the necessity and prominence of the topic is already well-known and adapted by the majority. Over the theory developed by Nitzan and Bichler, the concepts of capitalization, strategic sabotage, power, legitimacy, and obedience will be discussed. The hypothesis of “the absentee owners of the construction sector, holding the whip hand and capitalizing the ecology, control the growth and the creativity of green building production and make it carbon-dependent, in order to increase their profit margin” will be questioned. To strengthen the arguments in the hypothesis, the factors, the institutional arrangements, value measurement methods, which affect directly the net present value, will be investigated both in corporation and in building scale in detail, because net present value/ capitalization is asserted as the most important criteria by Nitzan and Bichler to make the investment decisions in the capitalist economic system. To trace the implications of power and the strategic sabotage that power caused, as the empirical dimension of this dissertation, an interface exploring the correlational ties between the climate responsive architecture and the ever changing political, economical, and social contexts and building economics praxis by decades will be developed and the expert interviews will be conducted with the design teams and the appraisers.
A parametric method for building design optimization based on Life Cycle Assessment - Appendix
(2016)
The building sector is responsible for a large share of human environmental impacts, over which architects and planners have a major influence. The main objective of this thesis is to develop a method for environmental building design optimization based on Life Cycle Assessment (LCA) that is applicable as part of the design process. The research approach includes a thorough analysis of LCA for buildings in relation to the architectural design stages and the establishment of a requirement catalogue. The key concept of the novel method called Parametric Life Cycle Assessment(PLCA) is to combine LCA with parametric design. The application of this method to three examples shows that building designs can be optimized time-efficiently and holistically from the beginning of the most influential early design stages, an achievement which has not been possible until now.
Tropical coral reefs, one of the world’s oldest ecosystems which support some of the highest levels of biodiversity on the planet, are currently facing an unprecedented ecological crisis during this massive human-activity-induced period of extinction. Hence, tropical reefs symbolically stand for the destructive effects of human activities on nature [4], [5]. Artificial reefs are excellent examples of how architectural design can be combined with ecosystem regeneration [6], [7], [8]. However, to work at the interface between the artificial and the complex and temporal nature of natural systems presents a challenge, i.a. in respect to the B-rep modelling legacy of computational modelling.
The presented doctorate investigates strategies on how to apply digital practice to realise what is an essential bulwark to retain reefs in impossibly challenging times. Beyond the main question of integrating computational modelling and high precision monitoring strategies in artificial coral reef design, this doctorate explores techniques, methods, and linking frameworks to support future research and practice in ecology led design contexts.
Considering the many existing approaches for artificial coral reefs design, one finds they often fall short in precisely understanding the relationships between architectural and ecological aspects (e.g. how a surface design and material composition can foster coral larvae settlement, or structural three-dimensionality enhance biodiversity) and lack an integrated underwater (UW) monitoring process. Such a process is necessary in order to gather knowledge about the ecosystem and make it available for design, and to learn whether artificial structures contribute to reef regeneration or rather harm the coral reef ecosystem.
For the research, empirical experimental methods were applied: Algorithmic coral reef design, high precision UW monitoring, computational modelling and simulation, and validated through parallel real-world physical experimentation – two Artificial Reef Prototypes (ARPs) in Gili Trawangan, Indonesia (2012–today). Multiple discrete methods and sub techniques were developed in seventeen computational experiments and applied in a way in which many are cross valid and integrated in an overall framework that is offered as a significant contribution to the field. Other main contributions include the Ecosystem-aware design approach, Key Performance Indicators (KPIs) for coral reef design, algorithmic design and fabrication of Biorock cathodes, new high precision UW monitoring strategies, long-term real-world constructed experiments, new digital analysis methods and two new front-end web-based tools for reef design and monitoring reefs. The methodological framework is a finding of the research that has many technical components that were tested and combined in this way for the very first time.
In summary, the thesis responds to the urgency and relevance in preserving marine species in tropical reefs during this massive extinction period by offering a differentiated approach towards artificial coral reefs – demonstrating the feasibility of digitally designing such ‘living architecture’ according to multiple context and performance parameters. It also provides an in-depth critical discussion of computational design and architecture in the context of ecosystem regeneration and Planetary Thinking. In that respect, the thesis functions as both theoretical and practical background for computational design, ecology and marine conservation – not only to foster the design of artificial coral reefs technically but also to provide essential criteria and techniques for conceiving them.
Keywords: Artificial coral reefs, computational modelling, high precision underwater monitoring, ecology in design.