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In this work, extensive reactive molecular dynamics simulations are conducted to analyze the nanopore creation by nano-particles impact over single-layer molybdenum disulfide (MoS2) with 1T and 2H phases. We also compare the results with graphene monolayer. In our simulations, nanosheets are exposed to a spherical rigid carbon projectile with high initial velocities ranging from 2 to 23 km/s. Results for three different structures are compared to examine the most critical factors in the perforation and resistance force during the impact. To analyze the perforation and impact resistance, kinetic energy and displacement time history of the projectile as well as perforation resistance force of the projectile are investigated.
Interestingly, although the elasticity module and tensile strength of the graphene are by almost five times higher than those of MoS2, the results demonstrate that 1T and 2H-MoS2 phases are more resistive to the impact loading and perforation than graphene. For the MoS2nanosheets, we realize that the 2H phase is more resistant to impact loading than the 1T counterpart.
Our reactive molecular dynamics results highlight that in addition to the strength and toughness, atomic structure is another crucial factor that can contribute substantially to impact resistance of 2D materials. The obtained results can be useful to guide the experimental setups for the nanopore creation in MoS2or other 2D lattices.
Durch internationale Fluchtbewegungen über die sogenannte Balkanroute bildete sich in Serbiens Hauptstadt Belgrad in den letzten Jahren ein sogenannter Refugee District heraus. Im Kontext von Migration und Flucht werden dabei zahlreiche Spannungsfelder auf unterschiedlichen räumlichen und politischen Ebenen sichtbar. Für Flüchtende kreieren diese eine Situation, die von Stillstand, Ausweglosigkeit, Kontrolle, Gefahr und Verdrängung geprägt ist. Allerdings führen die Vielschichtigkeit und die Diversität unterschiedlicher Akteur*innen, die bezüglich der Situation von Flüchtenden auf der Balkanroute wirkmächtig sind, auch zu Nischen, Widerständigkeiten und der Möglichkeit (neuer) Allianzen. Auf diese Weise entsteht eine kollektive Praktik der Nicht-Bewegung im Widerstand gegen die Unterdrückung und für globale Bewegungsfreiheit.
According to Eurocode, the computation of bending strength for steel cantilever beams is a straightforward process. The approach is based on an Ayrton-Perry formula adaptation of buckling curves for steel members in compression, which involves the computation of an elastic critical buckling load for considering the instability. NCCI documents offer a simplified formula to determine the critical bending moment for cantilevers beams with symmetric cross-section. Besides the NCCI recommendations, other approaches, e.g. research literature or Finite-Element-Analysis, may be employed to determine critical buckling loads. However, in certain cases they render different results. Present paper summarizes and compares the abovementioned analytical and numerical approaches for determining critical loads and it exemplarily analyses corresponding cantilever beam capacities using numerical approaches based on plastic zones theory (GMNIA).
The spread of breathing air when playing wind instruments and singing was investigated and visualized using two methods: (1) schlieren imaging with a schlieren mirror and (2) background-oriented schlieren (BOS). These methods visualize airflow by visualizing density gradients in transparent media. The playing of professional woodwind and brass instrument players, as well as professional classical trained singers were investigated to estimate the spread distances of the breathing air. For a better comparison and consistent measurement series, a single high note, a single low note, and an extract of a musical piece were investigated. Additionally, anemometry was used to determine the velocity of the spreading breathing air and the extent to which it was quantifiable. The results showed that the ejected airflow from the examined instruments and singers did not exceed a spreading range of 1.2 m into the room. However, differences in the various instruments have to be considered to assess properly the spread of the breathing air. The findings discussed below help to estimate the risk of cross-infection for wind instrument players and singers and to develop efficacious safety precautions, which is essential during critical health periods such as the current COVID-19 pandemic.
This paper presents numerical analysis of the discrete fundamental solution of the discrete Laplace operator on a rectangular lattice. Additionally, to provide estimates in interior and exterior domains, two different regularisations of the discrete fundamental solution are considered. Estimates for the absolute difference and lp-estimates are constructed for both regularisations. Thus, this work extends the classical results in the discrete potential theory to the case of a rectangular lattice and serves as a basis for future convergence analysis of the method of discrete potentials on rectangular lattices.
Global structural analyses in civil engineering are usually performed considering linear-elastic material behavior. However, for steel structures, a certain degree of plasticization depending on the member classification may be considered. Corresponding plastic analyses taking material nonlinearities into account are effectively realized using numerical methods. Frequently applied finite elements of two and three-dimensional models evaluate the plasticity at defined nodes using a yield surface, i.e. by a yield condition, hardening rule, and flow rule. Corresponding calculations are connected to a large numerical as well as time-consuming effort and they do not rely on the theoretical background of beam theory, to which the regulations of standards mainly correspond. For that reason, methods using beam elements (one-dimensional) combined with cross-sectional analyses are commonly applied for steel members in terms of plastic zones theories. In these approaches, plasticization is in general assessed by means of axial stress only. In this paper, more precise numerical representation of the combined stress states, i.e. axial and shear stresses, is presented and results of the proposed approach are validated and discussed.
Polylactic acid (PLA) is a highly applicable material that is used in 3D printers due to some significant features such as its deformation property and affordable cost. For improvement of the end-use quality, it is of significant importance to enhance the quality of fused filament fabrication (FFF)-printed objects in PLA. The purpose of this investigation was to boost toughness and to reduce the production cost of the FFF-printed tensile test samples with the desired part thickness. To remove the need for numerous and idle printing samples, the response surface method (RSM) was used. Statistical analysis was performed to deal with this concern by considering extruder temperature (ET), infill percentage (IP), and layer thickness (LT) as controlled factors. The artificial intelligence method of artificial neural network (ANN) and ANN-genetic algorithm (ANN-GA) were further developed to estimate the toughness, part thickness, and production-cost-dependent variables. Results were evaluated by correlation coefficient and RMSE values. According to the modeling results, ANN-GA as a hybrid machine learning (ML) technique could enhance the accuracy of modeling by about 7.5, 11.5, and 4.5% for toughness, part thickness, and production cost, respectively, in comparison with those for the single ANN method. On the other hand, the optimization results confirm that the optimized specimen is cost-effective and able to comparatively undergo deformation, which enables the usability of printed PLA objects.
Burning of clinker is the most influencing step of cement quality during the production process. Appropriate characterisation for quality control and decision-making is therefore the critical point to maintain a stable production but also for the development of alternative cements. Scanning electron microscopy (SEM) in combination with energy dispersive X-ray spectroscopy (EDX) delivers spatially resolved phase and chemical information for cement clinker. This data can be used to quantify phase fractions and chemical composition of identified phases.
The contribution aims to provide an overview of phase fraction quantification by semi-automatic phase segmentation using high-resolution backscattered electron (BSE) images and lower-resolved EDX element maps. Therefore, a tool for image analysis was developed that uses state-of-the-art algorithms for pixel-wise image segmentation and labelling in combination with a decision tree that allows searching for specific clinker phases. Results show that this tool can be applied to segment sub-micron scale clinker phases and to get a quantification of all phase fractions. In addition, statistical evaluation of the data is implemented within the tool to reveal whether the imaged area is representative for all clinker phases.
This study demonstrates the application and combination of multiple imaging techniques [light microscopy, micro-X-ray computer tomography (μ-CT), scanning electron microscopy (SEM) and focussed ion beam – nano-tomography (FIB-nT)] to the analysis of the microstructure of hydrated alite across multiple scales. However, by comparing findings with mercury intrusion porosimetry (MIP), it becomes obvious that the imaged 3D volumes and 2D images do not sufficiently overlap at certain scales to allow a continuous quantification of the pore size distribution (PSD). This can be overcome by improving the resolution and increasing the measured volume. Furthermore, results show that the fibrous morphology of calcium-silicate-hydrates (C-S-H) phases is preserved during FIB-nT. This is a requirement for characterisation of nano-scale porosity. Finally, it was proven that the combination of FIB-nT with energy-dispersive X-ray spectroscopy (EDX) data facilitates the phase segmentation of a 11 × 11 × 7.7 μm3 volume of hydrated alite.
Within the scope of literature, the influence of openings within the infill walls that are bounded by a reinforced concrete frame and excited by seismic drift forces in both in- and out-of-plane direction is still uncharted. Therefore, a 3D micromodel was developed and calibrated thereafter, to gain more insight in the topic. The micromodels were calibrated against their equivalent physical test specimens of in-plane, out-of-plane drift driven tests on frames with and without infill walls and openings, as well as out-of-plane bend test of masonry walls. Micromodels were rectified based on their behavior and damage states. As a result of the calibration process, it was found that micromodels were sensitive and insensitive to various parameters, regarding the model’s behavior and computational stability. It was found that, even within the same material model, some parameters had more effects when attributed to concrete rather than on masonry. Generally, the in-plane behavior of infilled frames was found to be largely governed by the interface material model. The out-of-plane masonry wall simulations were governed by the tensile strength of both the interface and masonry material model. Yet, the out-of-plane drift driven test was governed by the concrete material properties.
Realistic uncertainty description incorporating aleatoric and epistemic uncertainties can be described within the framework of polymorphic uncertainty, which is computationally demanding. Utilizing a domain decomposition approach for random field based uncertainty models the proposed level-based sampling method can reduce these computational costs significantly and shows good agreement with a standard sampling technique. While 2-level configurations tend to get unstable with decreasing sampling density 3-level setups show encouraging results for the investigated reliability analysis of a structural unit square.
Bauhaus-Gastprofessorin Mirjam Wenzel referierte am 30. Juni 2021 im Audimax der Bauhaus-Universität Weimar zur Entstehungsgeschichte und Konzeption Jüdischer Museen. Dabei ging sie darauf ein, inwiefern diese Museen besonders relevant für aktuelle gesellschaftliche und politische Fragestellungen sind. Prof. Wenzels zweiter öffentlicher Vortrag an der Bauhaus-Universität Weimar skizzierte die Potentiale von Kultureinrichtungen in Zeiten gesellschaftspolitischer Veränderungen im Allgemeinen und die Bedeutung Jüdischer Museen angesichts verbaler und tätlicher Gewalt gegen Jüdinnen und Juden im Besonderen.
Compiling and disseminating information about incidents and disasters are key to disaster management and relief. But due to inherent limitations of the acquisition process, the required information is often incomplete or missing altogether. To fill these gaps, citizen observations spread through social media are widely considered to be a promising source of relevant information, and many studies propose new methods to tap this resource. Yet, the overarching question of whether and under which circumstances social media can supply relevant information (both qualitatively and quantitatively) still remains unanswered. To shed some light on this question, we review 37 disaster and incident databases covering 27 incident types, compile a unified overview of the contained data and their collection processes, and identify the missing or incomplete information. The resulting data collection reveals six major use cases for social media analysis in incident data collection: (1) impact assessment and verification of model predictions, (2) narrative generation, (3) recruiting citizen volunteers, (4) supporting weakly institutionalized areas, (5) narrowing surveillance areas, and (6) reporting triggers for periodical surveillance. Furthermore, we discuss the benefits and shortcomings of using social media data for closing information gaps related to incidents and disasters.
Chemical glass frosting processes are widely used to create visual attractive glass surfaces. A commonly used frosting bath mainly contains ammonium bifluoride (NH4HF2) mixed with hydrochloric acid (HCl). The frosting process consists of several baths. Firstly, the preliminary bath to clean the object. Secondly, the frosting bath which etches the rough light scattering structure into the glass surface. Finally, the washing baths to clean the frosted object. This is where the constituents of the preceding steps accumulate and have to be filtered from the sewage. In the present contribution, phosphoric acid (H3PO4) was used as a substitute for HCl to reduce the amount of ammonium (NH4+) and chloride (Cl−) dissolved in the waste water. In combination with magnesium carbonate (MgCO3), it allows the precipitation of ammonium within the sewage as ammonium magnesium phosphate (MgNH4PO4). However, a trivial replacement of HCl by H3PO4 within the frosting process causes extensive frosting errors, such as inhomogeneous size distributions of the structures or domains that are not fully covered by these structures. By modifying the preliminary bath composition, it was possible to improve the frosting result considerably. To determine the optimal composition of the preliminary bath, a semi-automatic evaluation method has been developed. This method renders the objective comparison of the resulting surface quality possible.
Entrepreneurship and start-up activities are seen as a key response to recent upheavals in the media industry: Newly founded ventures can act as important drivers for industry transformation and renewal, pioneering new products, business models, and organizational designs (e.g. Achtenhagen, 2017; Buschow & Laugemann, 2020).
In principle, media students represent a crucial population of nascent entrepreneurs: individuals who will likely become founders of start-ups (Casero-Ripollés et al., 2016). However, their willingness to start a new business is generally considered to be rather low (Goyanes, 2015), and for journalism students, the idea of innovation tends to be conservative, following traditional norms and professional standards (Singer & Broersma, 2020). In a sample of Spanish journalism students, López-Meri et al. (2020) found that one of the main barriers to entrepreneurial intentions is that students feel they lack knowledge and training in entrepreneurship.
In the last 10 years, a wide variety of entrepreneurship education courses have been set up in media departments of colleges and universities worldwide.
These programs have been designed to sensitize and prepare communications, media and journalism students to think and act entrepreneurially (e.g. Caplan et al., 2020; Ferrier, 2013; Ferrier & Mays, 2017; Hunter & Nel, 2011). Entrepreneurial competencies
and practices not only play a crucial role for start-ups, but, in imes of digital transformation, are increasingly sought after by legacy media companies as well (Küng, 2015).
At the Department of Journalism and Communication Research, Hanover University of Music, Drama and Media, Germany, we have been addressing these developments with the “Media Entrepreneurship” program. The course, established in 2013, aims to provide fundamental knowledge of entrepreneurship, as well as promoting students‘ entrepreneurial thinking and behavior. This article presents the pedagogical approach of the program and investigates learning outcomes. By outlining and evaluating the Media Entrepreneurship program, this article aims to promote good practices of entrepreneurship education in communications, media and journalism, and to reflect on the limitations of such programs.
This article is focused on the research and development of new cellulose ether derivatives as innovative superplasticizers for mortar systems. Several synthetic strategies have been pursued to obtain new compounds to study their properties on cementitious systems as new bio-based additives. The new water-soluble admixtures were synthesized using a complex carboxymethylcellulose-based backbone that was first hydrolyzed and then sulfo-ethylated in the presence of sodium vinyl sulphonate. Starting with a complex biopolymer that is widely known as a thickening agent was very challenging. Only by varying the hydrolysis times and temperatures of the reactions was achieved the aimed goal. The obtained derivatives showed different molecular weight (Mw) and anionic charges on their backbones. An improvement in shear stress and dynamic viscosity values of CEM II 42.5R cement was observed with the samples obtained with a longer time of higher temperature hydrolysis and sulfo-ethylation. Investigations into the chemical nature of the pore solution, calorimetric studies and adsorption experiments clearly showed the ability of carboxymethyl cellulose superplasticizer (CMC SP) to interact with cement grains and influence hydration processes within a 48-h time window, causing a delay in hydration reactions in the samples. The fluidity of the cementitious matrices was ascertained through slump test and preliminary studies of mechanical and flexural strength of the hardened mortar formulated with the new ecological additives yielded values in terms of mechanical properties. Finally, the computed tomography (CT) images completed the investigation of the pore network structure of hardened specimens, highlighting their promising structure porosity.
The development of a hydro-mechanically coupled Coupled-Eulerian–Lagrangian (CEL) method and its application to the back-analysisof vibratory pile driving model tests in water-saturated sand is presented. The predicted pile penetration using this approachis in good agreement with the results of the model tests as well as with fully Lagrangian simulations. In terms of pore water pressure, however, the results of the CEL simulation show a slightly worse accordance with the model tests compared to the Lagrangian simulation. Some shortcomings of the hydro-mechanically coupled CEL method in case of frictional contact problems and pore fluids with high bulk modulus are discussed. Lastly, the CEL method is applied to the simulation of vibratory driving of open-profile piles under partially drained conditions to study installation-induced changes in the soil state. It is concluded that the proposed method is capable of realistically reproducing the most important mechanisms in the soil during the driving process despite its addressed shortcomings.
One of the most important subjects of hydraulic engineering is the reliable estimation of the transverse distribution in the rectangular channel of bed and wall shear stresses. This study makes use of the Tsallis entropy, genetic programming (GP) and adaptive neuro-fuzzy inference system (ANFIS) methods to assess the shear stress distribution (SSD) in the rectangular channel.
To evaluate the results of the Tsallis entropy, GP and ANFIS models, laboratory observations were used in which shear stress was measured using an optimized Preston tube. This is then used to measure the SSD in various aspect ratios in the rectangular channel. To investigate the shear stress percentage, 10 data series with a total of 112 different data for were used. The results of the sensitivity analysis show that the most influential parameter for the SSD in smooth rectangular channel is the dimensionless parameter B/H, Where the transverse coordinate is B, and the flow depth is H. With the parameters (b/B), (B/H) for the bed and (z/H), (B/H) for the wall as inputs, the modeling of the GP was better than the other one. Based on the analysis, it can be concluded that the use of GP and ANFIS algorithms is more effective in estimating shear stress in smooth rectangular channels than the Tsallis entropy-based equations.
This study proposes an efficient Bayesian, frequency-based damage identification approach to identify damages in cantilever structures with an acceptable error rate, even at high noise levels. The catenary poles of electric high-speed train systems were selected as a realistic case study to cover the objectives of this study. Compared to other frequency-based damage detection approaches described in the literature, the proposed approach is efficiently able to detect damages in cantilever structures to higher levels of damage detection, namely identifying both the damage location and severity using a low-cost structural health monitoring (SHM) system with a limited number of sensors; for example, accelerometers. The integration of Bayesian inference, as a stochastic framework, in the proposed approach, makes it possible to utilize the benefit of data fusion in merging the informative data from multiple damage features, which increases the quality and accuracy of the results. The findings provide the decision-maker with the information required to manage the maintenance, repair, or replacement procedures.
Biofeedback constitutes a well-established, non-invasive method to voluntary interfere in emotional processing by means of cognitive strategies. However, treatment durations exhibit strong inter-individual variations and first successes can often be achieved only after a large number of sessions. Sham feedback constitutes a rather untapped approach by providing feedback that does not correspond to the participant’s actual state. The current study aims to gain insights into mechanisms of sham feedback processing in order to support new techniques in biofeedback therapy. We carried out two experiments and applied different types of sham feedback on skin conductance responses and pupil size changes during affective processing. Results indicate that standardized but context-sensitive sham signals based on skin conductance responses exert a stronger influence on emotional regulation compared to individual sham feedback from ongoing pupil dynamics. Also, sham feedback should forego unnatural signal behavior to avoid irritation and skepticism among participants. Altogether, a reasonable combination of stimulus features and sham feedback characteristics enables to considerably reduce the actual bodily responsiveness already within a single session.