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In this work, extensive reactive molecular dynamics simulations are conducted to analyze the nanopore creation by nano-particles impact over single-layer molybdenum disulfide (MoS2) with 1T and 2H phases. We also compare the results with graphene monolayer. In our simulations, nanosheets are exposed to a spherical rigid carbon projectile with high initial velocities ranging from 2 to 23 km/s. Results for three different structures are compared to examine the most critical factors in the perforation and resistance force during the impact. To analyze the perforation and impact resistance, kinetic energy and displacement time history of the projectile as well as perforation resistance force of the projectile are investigated.
Interestingly, although the elasticity module and tensile strength of the graphene are by almost five times higher than those of MoS2, the results demonstrate that 1T and 2H-MoS2 phases are more resistive to the impact loading and perforation than graphene. For the MoS2nanosheets, we realize that the 2H phase is more resistant to impact loading than the 1T counterpart.
Our reactive molecular dynamics results highlight that in addition to the strength and toughness, atomic structure is another crucial factor that can contribute substantially to impact resistance of 2D materials. The obtained results can be useful to guide the experimental setups for the nanopore creation in MoS2or other 2D lattices.
Durch internationale Fluchtbewegungen über die sogenannte Balkanroute bildete sich in Serbiens Hauptstadt Belgrad in den letzten Jahren ein sogenannter Refugee District heraus. Im Kontext von Migration und Flucht werden dabei zahlreiche Spannungsfelder auf unterschiedlichen räumlichen und politischen Ebenen sichtbar. Für Flüchtende kreieren diese eine Situation, die von Stillstand, Ausweglosigkeit, Kontrolle, Gefahr und Verdrängung geprägt ist. Allerdings führen die Vielschichtigkeit und die Diversität unterschiedlicher Akteur*innen, die bezüglich der Situation von Flüchtenden auf der Balkanroute wirkmächtig sind, auch zu Nischen, Widerständigkeiten und der Möglichkeit (neuer) Allianzen. Auf diese Weise entsteht eine kollektive Praktik der Nicht-Bewegung im Widerstand gegen die Unterdrückung und für globale Bewegungsfreiheit.
According to Eurocode, the computation of bending strength for steel cantilever beams is a straightforward process. The approach is based on an Ayrton-Perry formula adaptation of buckling curves for steel members in compression, which involves the computation of an elastic critical buckling load for considering the instability. NCCI documents offer a simplified formula to determine the critical bending moment for cantilevers beams with symmetric cross-section. Besides the NCCI recommendations, other approaches, e.g. research literature or Finite-Element-Analysis, may be employed to determine critical buckling loads. However, in certain cases they render different results. Present paper summarizes and compares the abovementioned analytical and numerical approaches for determining critical loads and it exemplarily analyses corresponding cantilever beam capacities using numerical approaches based on plastic zones theory (GMNIA).
The spread of breathing air when playing wind instruments and singing was investigated and visualized using two methods: (1) schlieren imaging with a schlieren mirror and (2) background-oriented schlieren (BOS). These methods visualize airflow by visualizing density gradients in transparent media. The playing of professional woodwind and brass instrument players, as well as professional classical trained singers were investigated to estimate the spread distances of the breathing air. For a better comparison and consistent measurement series, a single high note, a single low note, and an extract of a musical piece were investigated. Additionally, anemometry was used to determine the velocity of the spreading breathing air and the extent to which it was quantifiable. The results showed that the ejected airflow from the examined instruments and singers did not exceed a spreading range of 1.2 m into the room. However, differences in the various instruments have to be considered to assess properly the spread of the breathing air. The findings discussed below help to estimate the risk of cross-infection for wind instrument players and singers and to develop efficacious safety precautions, which is essential during critical health periods such as the current COVID-19 pandemic.
This paper presents numerical analysis of the discrete fundamental solution of the discrete Laplace operator on a rectangular lattice. Additionally, to provide estimates in interior and exterior domains, two different regularisations of the discrete fundamental solution are considered. Estimates for the absolute difference and lp-estimates are constructed for both regularisations. Thus, this work extends the classical results in the discrete potential theory to the case of a rectangular lattice and serves as a basis for future convergence analysis of the method of discrete potentials on rectangular lattices.
Global structural analyses in civil engineering are usually performed considering linear-elastic material behavior. However, for steel structures, a certain degree of plasticization depending on the member classification may be considered. Corresponding plastic analyses taking material nonlinearities into account are effectively realized using numerical methods. Frequently applied finite elements of two and three-dimensional models evaluate the plasticity at defined nodes using a yield surface, i.e. by a yield condition, hardening rule, and flow rule. Corresponding calculations are connected to a large numerical as well as time-consuming effort and they do not rely on the theoretical background of beam theory, to which the regulations of standards mainly correspond. For that reason, methods using beam elements (one-dimensional) combined with cross-sectional analyses are commonly applied for steel members in terms of plastic zones theories. In these approaches, plasticization is in general assessed by means of axial stress only. In this paper, more precise numerical representation of the combined stress states, i.e. axial and shear stresses, is presented and results of the proposed approach are validated and discussed.
Polylactic acid (PLA) is a highly applicable material that is used in 3D printers due to some significant features such as its deformation property and affordable cost. For improvement of the end-use quality, it is of significant importance to enhance the quality of fused filament fabrication (FFF)-printed objects in PLA. The purpose of this investigation was to boost toughness and to reduce the production cost of the FFF-printed tensile test samples with the desired part thickness. To remove the need for numerous and idle printing samples, the response surface method (RSM) was used. Statistical analysis was performed to deal with this concern by considering extruder temperature (ET), infill percentage (IP), and layer thickness (LT) as controlled factors. The artificial intelligence method of artificial neural network (ANN) and ANN-genetic algorithm (ANN-GA) were further developed to estimate the toughness, part thickness, and production-cost-dependent variables. Results were evaluated by correlation coefficient and RMSE values. According to the modeling results, ANN-GA as a hybrid machine learning (ML) technique could enhance the accuracy of modeling by about 7.5, 11.5, and 4.5% for toughness, part thickness, and production cost, respectively, in comparison with those for the single ANN method. On the other hand, the optimization results confirm that the optimized specimen is cost-effective and able to comparatively undergo deformation, which enables the usability of printed PLA objects.
Burning of clinker is the most influencing step of cement quality during the production process. Appropriate characterisation for quality control and decision-making is therefore the critical point to maintain a stable production but also for the development of alternative cements. Scanning electron microscopy (SEM) in combination with energy dispersive X-ray spectroscopy (EDX) delivers spatially resolved phase and chemical information for cement clinker. This data can be used to quantify phase fractions and chemical composition of identified phases.
The contribution aims to provide an overview of phase fraction quantification by semi-automatic phase segmentation using high-resolution backscattered electron (BSE) images and lower-resolved EDX element maps. Therefore, a tool for image analysis was developed that uses state-of-the-art algorithms for pixel-wise image segmentation and labelling in combination with a decision tree that allows searching for specific clinker phases. Results show that this tool can be applied to segment sub-micron scale clinker phases and to get a quantification of all phase fractions. In addition, statistical evaluation of the data is implemented within the tool to reveal whether the imaged area is representative for all clinker phases.
This study demonstrates the application and combination of multiple imaging techniques [light microscopy, micro-X-ray computer tomography (μ-CT), scanning electron microscopy (SEM) and focussed ion beam – nano-tomography (FIB-nT)] to the analysis of the microstructure of hydrated alite across multiple scales. However, by comparing findings with mercury intrusion porosimetry (MIP), it becomes obvious that the imaged 3D volumes and 2D images do not sufficiently overlap at certain scales to allow a continuous quantification of the pore size distribution (PSD). This can be overcome by improving the resolution and increasing the measured volume. Furthermore, results show that the fibrous morphology of calcium-silicate-hydrates (C-S-H) phases is preserved during FIB-nT. This is a requirement for characterisation of nano-scale porosity. Finally, it was proven that the combination of FIB-nT with energy-dispersive X-ray spectroscopy (EDX) data facilitates the phase segmentation of a 11 × 11 × 7.7 μm3 volume of hydrated alite.
Within the scope of literature, the influence of openings within the infill walls that are bounded by a reinforced concrete frame and excited by seismic drift forces in both in- and out-of-plane direction is still uncharted. Therefore, a 3D micromodel was developed and calibrated thereafter, to gain more insight in the topic. The micromodels were calibrated against their equivalent physical test specimens of in-plane, out-of-plane drift driven tests on frames with and without infill walls and openings, as well as out-of-plane bend test of masonry walls. Micromodels were rectified based on their behavior and damage states. As a result of the calibration process, it was found that micromodels were sensitive and insensitive to various parameters, regarding the model’s behavior and computational stability. It was found that, even within the same material model, some parameters had more effects when attributed to concrete rather than on masonry. Generally, the in-plane behavior of infilled frames was found to be largely governed by the interface material model. The out-of-plane masonry wall simulations were governed by the tensile strength of both the interface and masonry material model. Yet, the out-of-plane drift driven test was governed by the concrete material properties.