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Schwerpunkt Medien der Natur
(2016)
Der Schwerpunkt der vorliegenden Ausgabe der ZMK – Medien der Natur – scheint den Medienbegriff aus den Grenzen herauslösen zu wollen, die seine konventionelle Semantik ihm auferlegt hat: aus den Grenzen der Kultur und der Geschichte bzw. der Kulturgeschichte. Man greife zu einer beliebigen älteren oder neueren Mediengeschichte – mag sie mit der Feuertelegraphie in Aischylos’ Agamemnon oder mit den Höhlenmalereien von Lascaux beginnen, eins steht auf jeden Fall fest: Medien sind technische Apparaturen und Installationen, und das heißt von Menschen geschaffene Artefakte, Zeugnisse der menschlichen Kultur. Weder enthalten handelsübliche Mediengeschichten die Beschreibung der Genexprimierung, obwohl Molekularbiologen sich dabei eines explizit medientechnischen Vokabulars wie cut-and-paste oder copy-and-paste bedienen, noch feiern sie die evolutionären Errungenschaften der Tierwelt in Sachen Medientechnik. Dabei ist der Zeichenaustausch zwischen Tieren, der Singvögel etwa oder der in Schwärmen und Völkern lebenden Tiere wie der Bienen, Ameisen und Fische schon lange bekannt und bewundert. In bestimmten Fällen ist der Stand der signal intelligence der Tiere von den Menschen aber auch erst sehr spät, während des Zweiten Weltkriegs, eingeholt worden. Motten aus der Familie der Arctiidae zum Beispiel senden ultrasonische Impulse aus, wenn sie insektivore Fledermäuse detektieren. Die die Motte verfolgende Fledermaus empfängt zwischen den Echos ihres von der Motte reflektierten eigenen Signals die von der Motte gesendeten Signale, und schnappt mithin nach einem akustischen Simulacrum der Motte auf halbem Wege zwischen sich und der eigentlichen Beute. Immerhin hat Michel Serres mit dem Parasiten ein aus der Medientheorie nicht mehr wegzudenkendes Konzept geschaffen – und Parasiten sind auch im biologischen Sinne, etwa als Bakterien, in ersten Ansätzen zum Thema der kulturwissenschaftlichen Medienforschung geworden. Die Operationen der Parasiten können durchaus für die Medienforschung anschluss- und ausbaufähig werden, wie etwa im Konzept des Zwischenwirts. Der Egel Leucochloridium paradoxum zum Beispiel, dessen endlicher Wirt Insekten fressende Vögel sind, muss seinen Zwischenwirt, eine Schnecke, auf die insektivore Vögel keinen Appetit haben, optisch in eine Raupe verwandeln (indem er sich in die Augenfühler der Schnecke schiebt), um an sein Ziel (den Vogelmagen) zu kommen.
To assess the safety impact of auxiliary lanes at downstream locations of U-turns, the Traffic Conflict Technique was used. On the basis of the installed components at those locations, four types of U-turns were identified: those without any auxiliary lane, those with an acceleration lane, those with outer widening, and those with both an acceleration lane and outer widening. The available crash data is unreliable, therefore to assess the level of road safety, Conflict Indexes were formulated to put more emphasis on severe crashes than on slight ones by using two types of weighting coefficients. The first coefficient was based on the subjective assessment of the seriousness of the conflict situation and the second was based on the relative speed and angle between conflicting streams. A comparatively higher Conflict Index value represents a lower level of road safety. According to the results, a lower level of road safety occurs if two components apply or if a location is without any auxiliary lane. The highest level of road safety occurs if the layout includes only a single component, either an acceleration lane or outer widening.
Die thermodynamischen Grundlagen der Hydratation von Hüttensand als Hauptbestandteil von Zementen werden erforscht. Hierbei werden thermodynamische Bildungs- und Reaktionsdaten experimentell bestimmt und berechnet. Darüber hinaus wird der Prozess der Feststoffauflösung von Hüttensand in wässrigen Lösungen untersucht. Lösungs- und Fällungsprozesse werden unter verschiedenen Konditionen gemessen, ausgewertet und diskutiert. Die Ergebnisse werden im weiteren Verlauf zur Bestimmung der Hydratationsgrades in Pasten sowie zum besseren Verständnis in der Wechselwirkung zwischen Hüttensanden und Mahlhilfsstoffen genutzt und angewandt.
In Zeiten volatiler Immobilienmärkte und einer hohen Wettbewerbsintensität sind leistungsfähige Systeme der Analyse und Entscheidungsunterstützung unverzichtbar. Entscheidungen zu Investitionsstrategien und Einzelinvestitionen basieren zumeist auf mehreren entscheidungsrelevanten Kriterien. Unterschiedliche immobilienwirtschaftliche Entscheidungsalternativen können dabei durchaus Kriterienausprägungen aufweisen, die eine bestimmte Alternative nicht als stets besser bzw. stets schlechter ausweisen. Klassische finanzwirtschaftliche Modelle oder verbreitete qualitative Verfahren wie das Scoring können die gegebene Komplexität meist nicht angemessen berücksichtigen. Eine Weiterentwicklung immobilienwirtschaftlicher Entscheidungsmodelle ist durch die Übertragung und Spezifizierung multikriterieller Verfahren der Entscheidungsunterstützung möglich. Speziell die Untergruppe des Outranking beschäftigt sich mit der schrittweisen Strukturierung, Ordnung und Priorisierung von komplexen Auswahlalternativen. Als spezifische immobilienwirtschaftliche Fragestellung dient hier die Auswahl und Priorisierung von Zielmärkten im taktischen Portfoliomanagement eines institutionellen Immobilienportfoliosmit internationaler Ausrichtung. Die Formalisierung des Entscheidungsproblems „Priorisierung von Zielmärkten“ erfolgt mit dem ELECTRE-Verfahren.
In vielen öffentlichen Gebäuden besteht ein hohes wirtschaftliches Einsparpotenzial bei den relevanten Energieträgern Wärme und Strom. Projekte zur energetischen Optimierungen refinanzieren sich häufig nach wenigen Jahren. Die notwenigen Investitionsmittel stehen jedoch nur begrenzt zur Verfügung. Zielgerichtete Analysen und Potenzialschätzungen sind erforderlich, um eine Priorisierung optionaler Maßnahmen zu erreichen. Die Studie zeigt anhand eines öffentlichen Portfolios notwendige Untersuchungsschritte auf. Die Einzelpotenziale werden über geeignete Benchmarks ermittelt. Auf Portfolioebene werden u. a. spezifische Potenzial-Matrizen genutzt. Die kennzahlenbasierte Priorisierung von Maßnahmen ist umso wichtiger, je stärker das Potenzial auf wenige Objekte konzentriert ist.
Die Bauinformatik ist eine Säule der modernen Bau- und Umweltingenieurwissenschaften und befasst sich mit der Erforschung grundlegender informatorischer Methoden sowie mit der Anwendung und Weiterentwicklung der Informationswissenschaften im Bau- und Umweltbereich. Der Arbeitskreis Bauinformatik konstituiert sich aus Wissenschaftlern, die an Universitäten im deutschsprachigen Raum auf dem Fachgebiet Bauinformatik lehren und forschen. Ausgehend vom erreichten Entwicklungsstand der Bauinformatik skizziert dieses Positionspapier die Aufgaben des Arbeitskreises und formuliert eine Grundlage für eine abgestimmte Weiterentwicklung an den deutschsprachigen Universitäten.
Paraffin Nanocomposites for Heat Management of Lithium-Ion Batteries: A Computational Investigation
(2016)
Lithium-ion (Li-ion) batteries are currently considered as vital components for advances in mobile technologies such as those in communications and transport. Nonetheless, Li-ion batteries suffer from temperature rises which sometimes lead to operational damages or may even cause fire. An appropriate solution to control the temperature changes during the operation of Li-ion batteries is to embed batteries inside a paraffin matrix to absorb and dissipate heat. In the present work, we aimed to investigate the possibility of making paraffin nanocomposites for better heat management of a Li-ion battery pack. To fulfill this aim, heat generation during a battery charging/discharging cycles was simulated using Newman’s well established electrochemical pseudo-2D model. We couple this model to a 3D heat transfer model to predict the temperature evolution during the battery operation. In the later model, we considered different paraffin nanocomposites structures made by the addition of graphene, carbon nanotubes, and fullerene by assuming the same thermal conductivity for all fillers. This way, our results mainly correlate with the geometry of the fillers. Our results assess the degree of enhancement in heat dissipation of Li-ion batteries through the use of paraffin nanocomposites. Our results may be used as a guide for experimental set-ups to improve the heat management of Li-ion batteries.
Cyber security has become a major concern for users and businesses alike. Cyberstalking and harassment have been identified as a growing anti-social problem. Besides detecting cyberstalking and harassment, there is the need to gather digital evidence, often by the victim. To this end, we provide an overview of and discuss relevant technological means, in particular coming from text analytics as well as machine learning, that are capable to address the above challenges. We present a framework for the detection of text-based cyberstalking and the role and challenges of some core techniques such as author identification, text classification and personalisation. We then discuss PAN, a network and evaluation initiative that focusses on digital text forensics, in particular author identification.
In this paper we introduce LUCI, a Lightweight Urban Calculation Interchange system, designed to bring the advantages of calculation and content co-ordination system to small planning and design groups by the means of an open source middle-ware. The middle-ware focuses on problems typical to urban planning and therefore features a geo-data repository as well as a job runtime administration, to coordinate simulation models and its multiple views. The described system architecture is accompanied by two exemplary use cases, that have been used to test and further develop our concepts and implementations.
In der Ph.D.-Arbeit wird gefragt, wie verschieden gestaltete Landschaften heute erlebt werden und wie sie auf die Menschen wirken. Dafür wird die Atmosphärentheorie erweitert und auf Landschaften angewendet. Atmosphären sind räumliche Stimmungsqualitäten, geprägt von der Umgebung, welche Menschen beeinflussen. Es wird ein Modell entwickelt, welches die Prägung von Atmosphären auf massiver, mobiler und ephemer Ebene beschreibt. Mit künstlerischen Arbeiten werden Atmosphären verschiedener anthropogener Landschaften übersetzt. Mit der exemplarischen wie theoretischen Bearbeitung von landschaftsverbundenen Atmosphären wird die Korrelation von Menschen und Umgebung nachgewiesen.
Der Bedarf an leistungsfähigen Hochgeschwindigkeits-Glasfasernetzen ist in den letzten Jahren, insbesondere aufgrund der zunehmenden Nutzung von Internet-basierten Diensten, rapide gestiegen. Eine umfassende Planung von neu zu errichtenden Glasfasernetzen im Sinne eines kostengünstigen Breitbandausbaus ist jedoch häufig mit hohem Aufwand verbunden. Die Auswahl möglicher Kabelwege und die anschließende Kalkulation der Installationskosten werden heute in der Regel durch computerbasierte Verfahren unterstützt, wobei allerdings die Installationspläne und die Installationskosten getrennt voneinander dargestellt werden, was wiederum die computergestützte Planung sowie weitere Optimierungsansätze erschwert. Dieses Arbeitspapier beschreibt ein Konzept für ein modulares Softwaresystem zur computergestützten Planung, Kostenkalkulation und Visualisierung von Glasfasernetzen, das eine integrierte Darstellung von Installationsplänen und Installationskosten ermöglicht. Anstelle der herkömmlichen Darstellung von Installationsplänen, die in der Regel alle geplanten Kabelwege einfarbig auf einer Landkarte visualisiert, wird ein Farbschema zur Anzeige der Installationskosten in Installationsplänen eingesetzt. Das Konzept wird prototypisch implementiert und durch ein Anwendungsbeispiel, das die Planung eines Glasfasernetzes innerhalb eines Siedlungsgebietes behandelt, validiert. Die integrierte, farbige Darstellung der Installationskosten in Installationsplänen ermöglicht eine effiziente Identifikation der kostenintensiven Bauabschnitte und befördert kostenoptimierte Planungsansätze. Die intuitive Visualisierung vereinfacht somit die akkurate und kostenoptimierte Planung von Glasfasernetzen.
Piezoelectric materials are used in several applications as sensors and actuators where they experience high stress and electric field concentrations as a result of which they may fail due to fracture. Though there are many analytical and experimental works on piezoelectric fracture mechanics. There are very few studies about damage detection, which is an interesting way to prevent the failure of these ceramics.
An iterative method to treat the inverse problem of detecting cracks and voids in piezoelectric structures is proposed. Extended finite element method (XFEM) is employed for solving the inverse problem as it allows the use of a single regular mesh for large number of iterations with different flaw geometries.
Firstly, minimization of cost function is performed by Multilevel Coordinate Search (MCS) method. The XFEM-MCS methodology is applied to two dimensional electromechanical problems where flaws considered are straight cracks and elliptical voids. Then a numerical method based on combination of classical shape derivative and level set method for front propagation used in structural optimization is utilized to minimize the cost function. The results obtained show that the XFEM-level set methodology is effectively able to determine the number of voids in a piezoelectric structure and its corresponding locations.
The XFEM-level set methodology is improved to solve the inverse problem of detecting inclusion interfaces in a piezoelectric structure. The material interfaces are implicitly represented by level sets which are identified by applying regularisation using total variation penalty terms. The formulation is presented for three dimensional structures and inclusions made of different materials are detected by using multiple level sets. The results obtained prove that the iterative procedure proposed can determine the location and approximate shape of material subdomains in the presence of higher noise levels.
Piezoelectric nanostructures exhibit size dependent properties because of surface elasticity and surface piezoelectricity. Initially a study to understand the influence of surface elasticity on optimization of nano elastic beams is performed. The boundary of the nano structure is implicitly represented by a level set function, which is considered as the design variable in the optimization process. Two objective functions, minimizing the total potential energy of a nanostructure subjected to a material volume constraint and minimizing the least square error compared to a target
displacement, are chosen for the numerical examples. The numerical examples demonstrate the importance of size and aspect ratio in determining how surface effects impact the optimized topology of nanobeams.
Finally a conventional cantilever energy harvester with a piezoelectric nano layer is analysed. The presence of surface piezoelectricity in nano beams and nano plates leads to increase in electromechanical coupling coefficient. Topology optimization of these piezoelectric structures in an energy harvesting device to further increase energy conversion using appropriately modified XFEM-level set algorithm is performed .
Im Kontext
(2016)
Die etymologische Herkunft des Wortes Kontext findet sich im lateinischen Begriff contexere, bedeutet somit zusammenweben, zusammenflechten. Während die immanente Deutung, z.B. eines Bildes oder einer Architektur, auf formale oder symbolische Aspekte und deren Verbindung zueinander abzielt, wird bei einer kontextuellen Betrachtungsweise der Blick außerhalb des Werkrahmens gelenkt. Etwas im Kontext zu betrachten bestimmt das Verständnis von Äußerungen und Gegenständen, da Zusammenhänge und Beziehungen sichtbar gemacht und aktiv hergestellt werden. Ein umfassenderer Blick wird gewährleistet, der das Objekt vielleicht in einem neuen Licht erscheinen lässt, oder aber auch die dazugehörige Umgebung. Nicht nur der Standpunkt der Betrachtung, auch wie nah oder fern man dem Betrachtungsgegenstand kommt, welchen Ausschnitt man wählt, aus welchem Erfahrungshorizont man an ihn herantritt – all dies beeinflusst letztlich das Ergebnis, sei es einer Deutung oder einer neuen Architektur, eines neuen Stadtteils etc. Der Kontext ist somit kein abgeschlossenes Konstrukt.
„Im Kontext“ ist ein Begriff, der gerade in Architektur und Städtebau von zentraler Bedeutung ist, und vielleicht gerade deshalb gewisse Abnutzungserscheinungen zeigt. Die Frage, inwiefern sich Neubauten in den architektonischen, stadträumlichen oder auch naturräumlichen „Kontext“ fügen (sollten), ist ein immer wiederkehrendes Thema in Architektur und Städtebau, über das leidenschaftlich gestritten wird und wurde. Heutzutage, wo es kaum noch Freiflächen gibt, steht alles in irgendeinem Kontext oder soll zumindest in diesem betrachtet werden. Wird in einer (historischen) Stadt eine Lücke geschlossen, so muss sich das Implantat „in den Kontext“ fügen, sei es architektonisch, räumlich, inhaltlich, historisch, konstruktiv, emotional, theoretisch… Hier hat der Kontext sicherlich auch seine Grenzen. Die Suche nach dem genius loci, nach einer Eigenart des Ortes, nach Traditionen und Kontinuität wird an manchen Orten, die bereits, um die berühmte Metapher Freuds zu bemühen, als Palimpsest erscheinen, geradezu zu einem Manierismus. "Im Kontext" darf also durchaus kritisch hinterfragt werden. Doch können wir deshalb auf die Frage nach dem Kontext verzichten? Gerade, wenn in der Gegenwart die historischen Zusammenhänge verloren zu gehen scheinen, wenn Bedeutungen losgelöst werden von ihrem historischen Gewordensein, kann es wichtig sein, diese wieder zu verankern.
Looking at our face in a mirror is one of the strongest phenomenological experiences of the Self in which we need to identify the face as reflected in the mirror as belonging to us. Recent behavioral and neuroimaging studies reported that self-face identification not only relies upon visual-mnemonic representation of ones own face but also upon continuous updating and integration of visuo-tactile signals. Therefore, bodily self-consciousness plays a major role in self-face identification, with respect to interplay between unisensory and multisensory processing. However, if previous studies demonstrated that the integration of multisensory body-related signals contributes to the visual processing of ones own face, there is so far no data regarding how self-face identification, inversely, contributes to bodily self-consciousness. In the present study, we tested whether selfother face identification impacts either the egocentered or heterocentered visuo-spatial mechanisms that are core processes of bodily self-consciousness and sustain selfother distinction. For that, we developed a new paradigm, named Double Mirror. This paradigm, consisting of a semi-transparent double mirror and computer-controlled Light Emitting Diodes, elicits selfother face merging illusory effect in ecologically more valid conditions, i.e., when participants are physically facing each other and interacting. Self-face identification was manipulated by exposing pairs of participants to an Interpersonal Visual Stimulation in which the reflection of their faces merged in the mirror. Participants simultaneously performed visuo-spatial and mental own-body transformation tasks centered on their own face (egocentered) or the face of their partner (heterocentered) in the pre- and post-stimulation phase. We show that selfother face identification altered the egocentered visuo-spatial mechanisms. Heterocentered coding was preserved. Our data suggest that changes in self-face identification induced a bottom-up conflict between the current visual representation and the stored mnemonic representation of ones own face which, in turn, top-down impacted bodily self-consciousness.
Problem definition and research objectives
1. The production of Portland cement clinker causes approx. 5% to 8% of the annual man-made CO2 emissions. This is due to the usage of mainly fossil fuel (approx. 40 % of the total CO2) and because of the decarbonation of limestone as a main component of the raw meal (approx. 60 % of the total CO2).
2. Various strategies are applied in order to reduce the green-house gas-emissions, such as optimizing the process of clinker production, the use of alternative fuel and the partial substitution of the clinker in blended cement by so-called SCM (supplementary cementitious materials). Hereby blast-furnace slag, fly ash and limestone are the most used materials.
3. Quaternary systems containing three SCM simultaneously besides Portland cement contribute to the reduction of CO2 emissions due to the decrease of the clinker content. In addition, such systems allow to use blast-furnace slag and fly ash in the most economical way and provide the possibility to account for shortages of SCM on the market.
4. Blast-furnace slag and fly ash show similarities in their principal chemical compositions such that similar hydrates are formed during their reaction in presence of Portland cement. Compared to ternary systems based on blast-furnace slag or fly ash besides limestone, quaternary systems that contain both, blast-furnace slag and fly ash, simultaneously besides limestone, are expected to perform similar in terms of phase assemblage and strength development.
5. The use of SCM as cement replacing materials is limited due to their generally slower reaction compared to neat cement which also leads to lower strength development, especially in the early stage of the hydration up to 28 d. To account for this it is necessary to study the reactivity of SCM such as blast-furnace slag and fly ash in detail in order to develop strategies to enhance the reactivity and thereby the strength development of SCM-containing systems.
6. The early hydration of clinker phases is studied in detail, mainly in diluted systems. It is unclear if processes that were found to control the reaction of such model systems are also prevailing in concentrated cement pastes under realistic water-to-solid ratios. Deeper insight to this aspect is needed to better understand interactions of neat Portland cement and SCM in the first hours of hydration.
State-of-the-art
7. Increasing Ca-concentrations lead to decreasing dissolution rates of C3S and C2S in diluted systems.
8. The hydration kinetics of C3S is controlled by the interplay of undersaturation with respect to C3S and oversaturation with respect to C-S-H.
9. Increasing Al-concentrations lead to a retardation of the hydration of C3S. It is unclear if the uptake of aluminum in C-S-H to form C-(A)-S-H which has a significantly lower growth rate than pure C-S-H or a retarding effect of Al on the dissolution of C3S causes this phenomenon.
10. The surface of limestone provides excellent conditions for the nucleation and growth of C-S-H such that significantly more C-S-H nuclei are formed in presence of limestone compared to other SCM.
11. The reactivity of blast-furnace slag and fly ash depends on the particle size as well as on the intrinsic reactivity of especially the amorphous phases.
12. An increase in network modifying oxides (e.g. CaO) in the chemical composition of amorphous (calcium)aluminosilicates leads to an increasingly depolymerized network which in turn causes increasing reactivity. The role of amphoteric oxides (Al2O3, Fe2O3) that can be present as network modifying oxides as well as network forming oxides is not completely solved.
13. CO2-containing AFm-phases are thermodynamically more stable than monosulfoaluminate. This indirectly stabilizes the voluminous ettringite which causes a higher total volume of hydrates and lower porosity whereby higher compressive strength is reached.
14. Only a few percent of limestone in blended cement reacts chemically dependent on the Al2O3 available for reaction. Al2O3 that is provided by the reaction of Portland cement but also by the dissolution of SCM, especially by fly ash, reacts to form hemicarboaluminate which is transformed to monocarboaluminate as the hydration proceeds.
Methodology
15. The influence of SCM on the early hydration of Portland cement in binary (including blast-furnace slag or fly ash or limestone or quartz) and ternary (including fly ash and limestone) systems was investigated applying isothermal calorimetry and analysis of the pore solution chemistry. Calculated saturation indices and solubility products of relevant phases were correlated with heat development. Based on the gained data it was reviewed if mechanisms that control the hydration of pure phases in diluted systems are also prevailing in cement pastes under realistic conditions.
16. The influence of the chemical composition of synthetic glasses on their dissolution at high pH was investigated in highly diluted systems using ion chromatography. Pozzolanity tests were conducted on pastes using simplified model systems and glass-blended Portland cements. The process of the glass dissolution was investigated by isothermal calorimetry and by thermogravimetry. Correlation of experimentally determined total bound water with bound water determined by mass balance calculations as a function of amount of glass reacted allowed to estimate the degree of glass reaction in the pastes. Further on selective dissolution experiments were carried out to crosscheck the results of the bound water/mass balance approach.
17. The reaction kinetics of quaternary pastes containing blast-furnace slag and fly ash simultaneously in the presence of limestone were investigated up to 28 d using isothermal calorimetry and chemical shrinkage measurements. In addition strength tests on mortar bars were carried out.
18. Pastes of quaternary blends were also investigated in terms of hydrate assemblage at ages of up to 182 d. Thermodynamic calculations regarding total volume of hydrates as a function of limestone and fly ash/blast-furnace slag content were conducted. The calculations were supported by thermogravimetric determination of bound water and portlandite content as well as qualitative X-ray diffraction. The results were correlated with strength tests on mortar bars.
19. The pore solutions of hydrated quaternary blends were extracted and investigated by means of ion chromatography at ages of up to 728 d. Based on the ion concentrations in the solutions saturation indices were calculated for relevant phases. In order to gain better insight to the blast-furnace slag reaction sulphate speciation was carried out at two blast furnace slag levels (20 and 30 wt.%) for selected samples up to 91 d of hydration and at 91 d for the whole matrix under investigation.
Main results
20. Investigations on the early hydration kinetics of binary systems showed a higher heat flow in presence of SCM compared to neat Portland cement. This is caused by the higher surface area that is available for the nucleation of hydrates and by the lower (over)saturation with respect to C-S-H. An increase in the Ca-concentration in the pore solution did not cause lower dissolution rates of C3S as was reported for pure phases in diluted systems. The highest dissolution was observed in the presence of limestone, i.e. at the highest Ca-concentration. The general trend of the reaction rate is inversely related to the degree of undersaturation with respect to C3S. The more undersaturated the faster the observed reaction. The presence of increasing Al-concentrations caused a retardation of the reaction which is in line with investigations on pure phases in diluted systems. Higher sulphate concentrations could be detected for the fly ash containing blend which possibly hindered ettringite precipitation and results in higher Al-concentrations. Correspondingly the low sulphate concentrations lead to lower Al-concentrations in the presence of quartz, blast-furnace slag and limestone compared to fly ash.
21. The early hydration kinetics of quaternary systems is significantly accelerated in the presence of limestone while fly ash leads to retardation. Compared to reference systems containing inert quartz, investigations by means of isothermal calorimetry and chemical shrinkage revealed an acceleration caused by blast-furnace slag. Additions of fly ash, limestone or mixtures thereof introduced another acceleration but differences are too small to be significant and clear distinguishing between the various SCM is not possible.
22. Investigations on the reactivity of synthetic glasses showed that increasing amounts of network modifying oxides caused an increase in reactivity and dissolution rates. The results reveal that Al2O3 acts mainly as network modifying oxide in all investigated glasses. Experimentally determined bound water (thermogravimetric experiments) in model systems and blended cements can be compared with bound water determined by mass balance calculations carried out as a function of the amount of glass reacted. This enables to estimate the degree of glass reaction.
23. The actual content of blast-furnace slag, fly ash or limestone does not exert significant influence on the development of compressive strength up to 7 d. At later ages thermodynamic calculations predict a degree of CaCO3 reaction of 2 to 5 wt.%. This leads to the formation of hemicarbonate and monocarbonate whereby ettringite is indirectly stabilized. As a result the total amount of solids is increased and compressive strength shows a slight maximum. Hereby the degree of CaCO3 reaction depends on the Al2O3 available for reaction which is not only provided by the dissolution of Portland cement but especially by the dissolution of the fly ash.
24. In general the presence of blast-furnace slag and fly ash in the presence of limestone exerts little influence on the hydrate assemblage. The substitution of some of the blast-furnace slag by fly ash leads to a slight decrease of portlandite and C-S-H and gives rise to the formation of more monocarbonate and hemicarbonate. Portlandite is consumed in a pozzolanic reaction with the fly ash whereby C-S-H is formed. However, the low reactivity of the fly ash causes a decrease in the amount of C-S-H formed. Thereby a lower total volume of hydrates is generated which is in line with slightly lower compressive strength in case of increasing fly ash content. The overall influence is small and all systems investigated reach strength class 42.5 N according to EN 196-1.
25. Corresponding to the investigations of the hydrate assemblage the pore solution chemistry of quaternary systems showed only small variations. Depending on the fly ash content the highest variations are observed for aluminium, i.e. increasing fly ash content leads to higher Al-concentrations. Another effect of increasing fly ash contents is an increasing undersaturation with respect to portlandite and a decreasing undersaturation with respect to strätlingite indicating the dissolution of portlandite.
26. The total concentration of sulfur in the pore solution is controlled by sulphate (SO42–) while the concentrations of sulphite (SO32–) and thiosulphate (S2O32–) were very low. Up to 2 d of hydration about 90 % of the total sulphur is present as SO42–. After 91 d this value is reduced to about 36 % while about 28 % are present as S2O32–. In general higher blast-furnace slag content leads to higher concentrations of sulphite and thiosulphate after 7 d.
The described study aims to find correlations between urban spatial configurations and human emotions. To this end, the authors measured people’s emotions while they walk along a path in an urban area using an instrument that measures skin conductance and skin temperature. The corresponding locations of the test persons were measured recorded by using a GPS-tracker (n=13). The results are interpreted and categorized as measures for positive and negative emotional arousal. To evaluate the technical and methodological process. The test results offer initial evidence that certain spaces or spatial sequences do cause positive or negative emotional arousal while others are relatively neutral. To achieve the goal of the study, the outcome was used as a basis for the study of testing correlations between people’s emotional responses and urban spatial configurations represented by Isovist properties of the urban form. By using their model the authors can explain negative emotional arousal for certain places, but they couldn’t find a model to predict emotional responses for individual spatial configurations.
In this work different fibre optic sensors for the structural health monitoring of civil engineering structures are reported. A fibre optic crack sensor and two different fibre optic moisture sensors have been designed to detect the moisture ingress in concrete based building structures. Moreover, the degeneration of the mechanical properties of optical glass fibre sensors and hence their long-term stability and reliability due to the mechanical and chemical impact of the concrete environment is discussed as well as the advantage of applying a fibre optic sensor system for the structural health monitoring of sewerage tunnels is demonstrated.