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Polymer modification of mortar and concrete is a widely used technique in order to improve their durability properties. Hitherto, the main application fields of such materials are repair and restoration of buildings. However, due to the constant increment of service life requirements and the cost efficiency, polymer modified concrete (PCC) is also used for construction purposes. Therefore, there is a demand for studying the mechanical properties of PCC and entitative differences compared to conventional concrete (CC). It is significant to investigate whether all the assumed hypotheses and existing analytical formulations about CC are also valid for PCC. In the present study, analytical models available in the literature are evaluated. These models are used for estimating mechanical properties of concrete. The investigated property in this study is the modulus of elasticity, which is estimated with respect to the value of compressive strength. One existing database was extended and adapted for polymer-modified concrete mixtures along with their experimentally measured mechanical properties. Based on the indexed data a comparison between model predictions and experiments was conducted by calculation of forecast errors.
Research into bio-based epoxy resins has intensified in recent decades. Here, it is of great importance to use raw materials whose use does not compete with food production. In addition, the performance of the newly developed materials should be comparable to that of conventional products. Possible starting materials are lignin degradation products, such as vanillin and syringaldehyde, for which new synthesis routes to the desired products must be found and their properties determined. In this article, the first synthesis of two amine hardeners, starting with vanillin and syringaldehyde, using the Smiles rearrangement reaction is reported. The amine hardeners were mixed with bisphenol A diglycidyl ether, and the curing was compared to isophorone diamine, 4-4′-diaminodiphenyl sulfone, and 4-Aminonbenzylamine by means of differential scanning calorimetry. It was found that the two amines prepared are cold-curing. As TG-MS studies showed, the thermal stability of at least one of the polymers prepared with the potentially bio-based amines is comparable to that of the polymer prepared with isophorone diamine, and similar degradation products are formed during pyrolysis.