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- OA-Publikationsfonds2023 (19) (remove)
Research into bio-based epoxy resins has intensified in recent decades. Here, it is of great importance to use raw materials whose use does not compete with food production. In addition, the performance of the newly developed materials should be comparable to that of conventional products. Possible starting materials are lignin degradation products, such as vanillin and syringaldehyde, for which new synthesis routes to the desired products must be found and their properties determined. In this article, the first synthesis of two amine hardeners, starting with vanillin and syringaldehyde, using the Smiles rearrangement reaction is reported. The amine hardeners were mixed with bisphenol A diglycidyl ether, and the curing was compared to isophorone diamine, 4-4′-diaminodiphenyl sulfone, and 4-Aminonbenzylamine by means of differential scanning calorimetry. It was found that the two amines prepared are cold-curing. As TG-MS studies showed, the thermal stability of at least one of the polymers prepared with the potentially bio-based amines is comparable to that of the polymer prepared with isophorone diamine, and similar degradation products are formed during pyrolysis.
When predicting sound pressure levels induced by structure-borne sound sources and describing the sound propagation path through the building structure as exactly as possible, it is necessary to characterize the vibration behavior of the structure-borne sound sources. In this investigation, the characterization of structure-borne sound sources was performed using the two-stage method (TSM) described in EN 15657. Four different structure-borne sound sources were characterized and subsequently installed in a lightweight test stand. The resulting sound pressure levels in an adjacent receiving room were measured. In the second step, sound pressure levels were predicted according to EN 12354-5 based on the parameters of the structure-borne sound sources. Subsequently, the predicted and the measured sound pressure levels were compared to obtain reliable statements on the achievable accuracy when using source quantities determined by TSM with this prediction method.
Dass Lobby-Arbeit auch für Bibliotheken und damit auch für Bibliothekar:innen unverzichtbar ist, hat sich als Erkenntnis mittlerweile durchgesetzt. Im Folgenden soll – ausgehend von einer kurzen Betrachtung des Stellenwerts der Lobbyarbeit in der bibliothekarischen Verbandsarbeit – aufgezeigt werden, welche Rolle Lobbyaktivitäten im bibliothekarischen Alltag spielen könnten bzw. sollten.
SOS-Signale auf hoher See, Klopfzeichen in Trümmerfeldern, Flaschenposten am Strand: Wenn Menschen in Not geraten, müssen sie mit allen Mitteln auf sich aufmerksam machen. Sie müssen Lebenszeichen senden, um am Leben zu bleiben. Dieses Buch erforscht das Phänomen des Lebenszeichens erstmals aus der Perspektive von Medienkulturwissenschaft, Zeichentheorie und Existenzphilosophie. Anhand zahlreicher Katastrophenszenarien wie Erdbeben, Lawinen und Bergwerkunglücken zeigt die Studie, warum Menschen in Not existenziell von Medien und Kommunikationsmitteln abhängen: Keine Lebenszeichen ohne Signalfackeln, Peilsender, Satelliten oder Infrarotsensoren. Medien in Notfällen sind mehr als nur Mittel zur Kommunikation, sie sind Bedingungen menschlicher Existenz. Sie entscheiden, ob und wie sich Leben in Not äußern kann, ob Lebenszeichen Gehör finden und ob Leben gerettet wird. Damit werfen Lebenszeichen ein neues Licht auf die elementaren Bedingungen menschlichen Lebens: Sie zeigen uns, dass Menschen in Not nur überleben, wenn sie mit Artefakten, Netzwerken und Infrastrukturen verbunden sind, die ihre Existenz ermöglichen.
Urban Heat Transition in Berlin: Corporate Strategies, Political Conflicts, and Just Solutions
(2023)
In the field of urban climate policy, heat production and demand are key sectors for achieving a sustainable city. Heat production has to shift from fossil to renewable energies, and the heat demand of most buildings has to be reduced significantly via building retrofits. However, analyses of heat transition still lack its contextualization within entangled urban politico-economic processes and materialities and require critical socio-theoretical examination. Asking about the embeddedness of heat transition within social relations and its implications for social justice issues, this article discusses the challenges and opportunities of heat transition, taking Berlin as an example. It uses an urban political ecology perspective to analyze the materialities of Berlin’s heating-housing nexus, its politico-economic context, implications for relations of inequality and power, and its contested strategies. The empirical analysis identifies major disputes about the future trajectory of heat production and about the distribution of retrofit costs. Using our conceptual approach, we discuss these empirical findings against the idea of a more just heat transition. For this purpose, we discuss three policy proposals regarding cost distribution, urban heat planning, and remunicipalization of heat utilities. We argue that this conceptual approach provides huge benefits for debates around heat transition and, more generally, energy justice and just transitions.
The imperative to transform current energy provisions is widely acknowledged. However, scant attention has hitherto been directed toward rural municipalities and their innate resources, notably biogenic resources. In this paper, a methodological framework is developed to interconnect resources from waste, wastewater, and agricultural domains for energy utilization. This entails cataloging existing resources, delineating their potential via quantitative assessments utilizing diverse technologies, and encapsulating them in a conceptual model. The formulated models underwent iterative evaluation with engagement from diverse stakeholders. Consequently, 3 main concepts, complemented by 72 sub-concepts, were delineated, all fostering positive contributions to climate protection and providing heat supply in the rural study area. The outcomes’ replicability is underscored by the study area’s generic structure and the employed methodology. Through these inquiries, a framework for the requisite energy transition, with a pronounced emphasis on the coupling of waste, wastewater, and agriculture sectors in rural environments, is robustly analyzed.
Calcined clays are interesting starting materials to be used as SCMs (supplementary cementitious materials) in cements or to be converted to geopolymers by activation with a high alkaline activator. The adjustment of the properties in the fresh state, especially regarding the consistency of these binders, is almost exclusively achieved by the addition of water, since commercially available superplasticizers seem to be ineffective in low-calcium geopolymer systems. The aim of this study was a systematic investigation of various PCE (polycarboxylate ester/ether) superplasticizers (methacrylate ester PCE: MPEG, isoprenol ether PCE: IPEG, methallyl ether PCE: HPEG) with respect to their stability in different alkaline activators (NaOH, KOH, sodium and potassium silicate solutions). The effectiveness of superplasticizers (SPs) in low-calcium geopolymer binders was verified by rheological tests. Size exclusion chromatography was used to investigate if structural degradation of the superplasticizers occurs. The investigated PCE superplasticizers showed a thickening effect in the low-calcium geopolymer system. Depending on the alkalinity of the activator solution, a degradation process was detected for all the PCEs investigated. The side chains of the PCEs are cleaved off the backbone by basic ester and ether hydrolysis. The highest degree of degradation was found in sodium and potassium silicate solutions. In alkaline hydroxide solutions, the degradation process increases with increasing alkalinity.
Antimicrobial resistances (AMR) are ranked among the top ten threats to public health and societal development worldwide. Toilet wastewater contained in domestic wastewater is a significant source of AMR entering the aquatic environment. The current commonly implemented combined sewer systems at times cause overflows during rain events, resulting in the discharge of untreated wastewater into the aquatic environment, thus promoting AMR. In this short research article, we describe an approach to transform combined sewer systems into source separation-modified combined sewer systems that separately treat toilet wastewater. We employ simulations for demonstrating that source separation-modified combined sewer systems reduce the emission of AMR- causing substances by up to 11.5 logarithm levels. Thus, source separation- modified combined sewer systems are amongst the most effective means of combating AMR.
KEYWORDS
The study presents a Machine Learning (ML)-based framework designed to forecast the stress-strain relationship of arc-direct energy deposited mild steel. Based on microstructural characteristics previously extracted using microscopy and X-ray diffraction, approximately 1000 new parameter sets are generated by applying the Latin Hypercube Sampling Method (LHSM). For each parameter set, a Representative Volume Element (RVE) is synthetically created via Voronoi Tessellation. Input raw data for ML-based algorithms comprises these parameter sets or RVE-images, while output raw data includes their corresponding stress-strain relationships calculated after a Finite Element (FE) procedure. Input data undergoes preprocessing involving standardization, feature selection, and image resizing. Similarly, the stress-strain curves, initially unsuitable for training traditional ML algorithms, are preprocessed using cubic splines and occasionally Principal Component Analysis (PCA). The later part of the study focuses on employing multiple ML algorithms, utilizing two main models. The first model predicts stress-strain curves based on microstructural parameters, while the second model does so solely from RVE images. The most accurate prediction yields a Root Mean Squared Error of around 5 MPa, approximately 1% of the yield stress. This outcome suggests that ML models offer precise and efficient methods for characterizing dual-phase steels, establishing a framework for accurate results in material analysis.
Der Erfahrung auf der Spur
(2023)
Dieselbe Zeit, derselbe Raum - zwei, grundverschiedene Regisseure und damit Erfahrungswelten. Aleksandr Rastorguevs und Sergei Loznitsas Dokumentarfilme der 90er und 2000er Jahre sind politische, poetische, punktgenaue Interventionen in die Gegenwart der „kleinen Menschen“. Das Buch widmet sich dokumentarfilmischen Meisterwerken, die methodisch Verdrängtes und Übersehenes, planmäßig Vergessenes sichtbar machen – nach dem Krieg ist vor dem Krieg. Ästhetik in ihrer sozial-, geschichts- und kulturwissenschaftlichen Relevanz.
Im post- und kontrafaktischen Zeitalter des allgegenwärtigen medialen Überflusses, inmitten der Fernseh-, YouTube- und virtuellen Realität, erfüllen, begründen, ermöglichen oder schlichtweg erkämpfen die Filme und ihre Autoren verloren gegangene Räume für Widersprüche, Fragen, die mal in ihrer Ambivalenz, mal in ihrer spröden Eindeutigkeit ihren Aussagewert haben. Wider die marginale Rezeption rückt die Publikation sie in den Raum der interdisziplinären wissenschaftlichen Forschung und stellt sie als gleichwertige Formen der Wissens- und Erfahrungsproduktion vor.
Bei all ihrer Unterschiedlichkeit, katapultieren die Filme den Zuschauer in ebenjene bekannte, aber nicht erkannte, weil nicht gesehene, übersehene, nicht wahrgenommene Hyperrealität ihrer Alltagswirklichkeit. Weder der Autor noch das Werk noch der Zuschauer sind aus dem jeweiligen historischen oder soziopolitischen Diktum herauslösbar oder gar gänzlich frei.