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- 2010 (17) (remove)
Die vorliegende Arbeit beschäftigt sich mit der geometrischen Suffosionsbeständigkeit von Erdstoffen. Mit dem wahrscheinlichkeitstheoretischen Ansatz der Perkolationstheorie wurde ein analytisches Verfahren gewählt, mit dem suffosive Materialtransportprozesse modelliert und quantifiziert werden können. Mit dem verwendeten Perkolationsmodell wurde eine beliebige Porenstruktur eines realen Erdstoffes im 3-Dimensionalen modelliert. Mögliche Materialtransportprozesse innerhalb der modellierten Porenstruktur wurden anschließend simuliert. Allgemein gültige Gesetzmäßigkeiten wurden hergeleitet und Grenzbedingungen formuliert. Diese sind vom Erdstoff unabhängig und beschreiben Zusammenhänge zwischen Materialtransport und Porenstruktur. Anwendbar sind diese Ergebnisse auf homogene, isotrope und selbstähnliche Erdstoffgefüge. Aussagen über konkrete Erdstoffe können über die Transformationsmethode erfolgen. Für die Verwendung der Transformationsmethode ist vorab die relevante Porenstruktur, d. h. die Porenengstellenverteilung, zu ermitteln.
Verkehrsmengenrisiko bei PPP-Projekten im Straßensektor - Determinanten effizienter Risikoallokation
(2010)
Trotz weltweit umfangreichen Erfahrungen mit Public Private Partnership Projekten im Straßensektor bleibt der Umgang mit dem Verkehrsmengenrisiko für die Projektbeteiligten eine Herausforderung. Die Arbeit widmet sich daher der wesentlichen Fragestellung nach einer effizienten Allokation dieses Risikos, dem nicht weniger Bedeutung zukommt als für den gesamtwirtschaftlichen Erfolg eines Straßenkonzessionsprojektes eine entscheidende Rolle zu spielen. Untersucht werden zunächst die Charakteristika des Verkehrsmengenrisikos mit seinen umfänglichen Einflussfaktoren. Anschließend werden die in der Praxis zur Anwendung kommenden Vertragsmodelle zur Bewirtschaftung von Straßeninfrastruktur dargestellt und analysiert, wie in den einzelnen Modellen Verkehrsmengenrisiko auf die verschiedenen Vertragspartner verteilt wird. Auf Basis dieser Grundlagen wird ein kriteriengestützter Analyserahmen entwickelt, der die Effizienz unterschiedlicher Risikoallokationen zwischen den Vertragspartner bewertet. Dabei werden einerseits die effizienzbeeinflussenden Eigenschaften der potentiellen Risikoträger eines PPP-Projektes berücksichtigt als auch die die effizienzbeeinflussenden Wirkungen der unterschiedlichen Vertragsmodelle. Aus den Erkenntnissen dieser Analyse werden letztlich Handlungs- und Gestaltungsempfehlungen zum Umgang mit dem Verkehrsmengenrisiko abgeleitet.
Die Behandlung von geometrischen Singularitäten bei der Lösung von Randwertaufgaben der Elastostatik stellt erhöhte Anforderungen an die mathematische Modellierung des Randwertproblems und erfordert für eine effiziente Auswertung speziell angepasste Berechnungsverfahren. Diese Arbeit beschäftigt sich mit der systematischen Verallgemeinerung der Methode der komplexen Spannungsfunktionen auf den Raum, wobei der Schwerpunkt in erster Linie auf der Begründung des mathematischen Verfahrens unter besonderer Berücksichtigung der praktischen Anwendbarkeit liegt. Den theoretischen Rahmen hierfür bildet die Theorie quaternionenwertiger Funktionen. Dementsprechend wird die Klasse der monogenen Funktionen als Grundlage verwendet, um im ersten Teil der Arbeit ein räumliches Analogon zum Darstellungssatz von Goursat zu beweisen und verallgemeinerte Kolosov-Muskhelishvili Formeln zu konstruieren. Im Hinblick auf die vielfältigen Anwendungsbereiche der Methode beschäftigt sich der zweite Teil der Arbeit mit der lokalen und globalen Approximation von monogenen Funktionen. Hierzu werden vollständige Orthogonalsysteme monogener Kugelfunktionen konstruiert, infolge dessen neuartige Darstellungen der kanonischen Reihenentwicklungen (Taylor, Fourier, Laurent) definiert werden. In Analogie zu den komplexen Potenz- und Laurentreihen auf der Grundlage der holomorphen z-Potenzen werden durch diese monogenen Orthogonalreihen alle wesentlichen Eigenschaften bezüglich der hyperkomplexen Ableitung und der monogenen Stammfunktion verallgemeinert. Anhand repräsentativer Beispiele werden die qualitativen und numerischen Eigenschaften der entwickelten funktionentheoretischen Verfahren abschließend evaluiert. In diesem Kontext werden ferner einige weiterführende Anwendungsbereiche im Rahmen der räumlichen Funktionentheorie betrachtet, welche die speziellen Struktureigenschaften der monogenen Potenz- und Laurentreihenentwicklungen benötigen.
Der Siedlungsbau in Hanoi kan heutzutage - über 20 Jahre nach dem Beginn der Renovierungspolitik udn der Markwirtschaft, die dem Städtebau eine große Gelegenheit zur Verbesserung gegeben haben - zurückblickend und eingeschätz werden. Die letzten 20 Jahre sind eine kurze Zeit in der tausendjährigen Geschichte der Stadt, trotzdem entwickelte sich die Stadt in diesem Zeitraum am schnellsten und auch am problematischten aus Sicht der Umwelt. Ohne eine passende Entwicklungsstategie oder eine geeignete Maßnahme bei der Stadtplanung vergrößert sich der Konflikt Ökonomie - Ökologie immer weiter. ... Die Findung eines neuen Wohnkonzeptes im Gleichgewicht zwischen Ökonomie und der Ökologie ist eine hochaktuelle Frage geworden.
This cumulative dissertation investigates aspects of consumer decision making in hedonic contexts and its implications for the marketing of media goods through a series of three empirical studies. All three studies take place within a common theoretical framework of decision making models, applying parts of the framework in novel ways to solve real-world marketing research problems (study 1 and 2), and examining theoretical relationships between variables within of the framework (study 3). One notable way in which the studies differ is their theoretical treatment of the hedonic component of decision making, i.e. the role and conceptualization of emotions.
In the last two decades, many cities have faced changes in their economic basis and therefore adopted an entrepreneurial approach in the municipal administration accompanied by city marketing strategies. Brazilian cities have also adopted this approach, like the case of Florianópolis. Florianópolis has promoted advertising campaigns on the natural resources of the Island of Santa Catarina as well as on its quality of life in comparison to other cities. However, due also to such campaigns, it has experienced a great demographic growth and, consequently, infrastructural and social problems. Nevertheless, it seems to have a good image within the national urban scenario and has been commonly considered an “urban consumption dream” for many Brazilians. This paradoxical situation is the reason why it has been chosen as the research object in this dissertation. Thus, the questions of this research are: is there a gap between the promise and the performance of the city of Florianópolis? If so, can tourists and residents recognize it? And finally, how can this gap be demonstrated? Accordingly, the main objective of this research is to propose a conformity assessment approach applicable to cities, by which the content of city advertisement campaigns can be compared to its performance indicators and satisfaction degree of its consumers. Therefore, this approach is composed by different methods: literature and legislation reviews, semi-structured and structured interviews with experts and inhabitants, an urban centrality development analysis, a qualitative discourse analysis of advertising material (including images), a qualitative content analysis of newspaper reports and a questionnaire survey. Finally, the theses are: yes, there is a gap between promise and performance of Florianópolis; this promise is a result of city marketing campaigns which advertise its natural features and at the same time hiding its urban aspects, supported by some political and private actors, mainly interested in the development of tourism and real estate market in the city; this gap has been already recognized by tourists and more intensively by residents; the selected methods worked as a kind of conformity assessment for cities and tourist destinations; and last but not least, since there is a gap, it designates the practice of “make-up urbanism”. Research limitations are the short time frame covered by this analysis and small and non-representative samples. However, its relevance lies in the attempt to fill in two disciplinary lacunas: a conformity assessment approach for cities and the creation of knowledge about Florianópolis and its further presentation at an international level, on the one hand. On the other hand, the transfer of this approach to other cities would help explaining a (common) contemporary urban phenomenon and appeal for more ethical conduct and transparency in the practices of city marketing.
In this dissertation, a new, unique and original biaxial device for testing unsaturated soil was designed and developed. A study on the mechanical behaviour of unsaturated sand in plane-strain conditions using the new device is presented. The tests were mainly conducted on Hostun sand specimens. A series of experiments including basic characterisation, soil water characteristic curves, and compression biaxial tests on dry, saturated, and unsaturated sand were conducted. A set of bearing capacity tests of strip model footing on unsaturated sand were performed. Additionally, since the presence of fine content (i.e., clay) influences the behavior of soils, soil water characteristic tests were also performed for sand-kaolin mixtures specimens.
Seit 1969 werden für die Bundesrepublik kontinuierlich Berechnungen zu den Gesamtkosten des Straßenverkehrs der Bundesfernstraßen und deren Verteilung auf die Verkehrsteilnehmer durchgeführt. Die Ergebnisse der Wegekostenrechnungen der Jahre 2002 und 2007 sind die Grundlage für die mittlerweile für das deutsche Autobahnnetz eingeführte fahrleistungsbezogene Benutzungsgebühr für Lkw mit einem zulässigen Gesamtgewicht von mindestens zwölf Tonnen. Damit wird die Forderung der EU-Richtlinie 1999/62/EG umgesetzt, nach der sich die durchschnittlichen Straßenbenutzungsgebühren an den Kosten für den Bau, den Betrieb und den Ausbau des betreffenden Verkehrswegenetzes orientieren sollen. Mit der EU-Richtlinie 2006/38/EG kündigt sich die weitere Entwicklung bei der Berechnung von Straßenbenutzungsgebühren an. Zukünftig sollen auch externe Kosten in die Berechnung einfließen. Ein erster Schritt zur Berücksichtigung dieser externen Kosten erfolgte mit Erstellung eines Handbuchs im Rahmen eines EU-Forschungsprojektes. Das Handbuch enthält aufgrund der unterschiedlichen Rahmenbedingungen in den Mitgliedsstaaten der EU keine exakten Berechnungsvorschriften, sondern stellt verschiedene methodische Ansätze bisher durchgeführter Studien zu externen Kosten vor, gibt Empfehlungen hinsichtlich der Methodenwahl und beinhaltet Schätzungen über die Höhe der externen Kosten. Die im europäischen Raum in den vergangenen Jahren durchgeführten Studien zur Ermittlung externer Kosten des Verkehrs zeichnen sich durch einander ähnelnde Vorgehensweisen aus, die aber vor allem hinsichtlich der Kostenrechnungsart und der verwendeten Kostensätze aus Sicht des Verfassers der vorliegenden Arbeit kritische Aspekte aufweisen. In der vorliegenden Dissertationsschrift wird daher eine alternative Berechnungsmethodik zur Ermittlung abschnitts-, fahrzeugklassen- und fahrleistungsbezogener externer Kosten für Autobahnen entwickelt und an einem ausgewählten Beispielnetz zur Anwendung gebracht. Dabei wird in einigen wesentlichen Punkten von der in aktuellen Studien überwiegend gewählten Vorgehensweise abgewichen, um eine andere Sichtweise darzustellen. Damit trägt die vorliegende Arbeit substanziell zur Erweiterung des Erkenntnisstands zu Berechnungsmethoden externer Kosten des Straßenverkehrs bei. Die hier entwickelte Berechnungsmethodik ist außerdem als Grundlage für ein in der Praxis anwendbares Verfahren zu verstehen und zeichnet sich auch daher durch eine einfach zu handhabende Übertragbarkeit auf das gesamte Autobahnnetz Deutschlands aus. Die Abschnitte entsprechen den Teilstrecken zwischen zwei Autobahnanschlussstellen. Es wird zwischen den beiden Fahrzeugklassen "Lkw ab 12 t zulässigem Gesamtgewicht" und "Sonstigen Fahrzeugen" unterschieden. Obwohl momentan nur eine Benutzungsgebühr für Lkw ab 12 t zulässigem Gesamtgewicht erhoben wird, ist es mit der entwickelten Methodik möglich, fahrleistungsbezogene externe Kosten für alle Kfz angeben zu können. Die Einbeziehung externer Nutzen wird in diesem Zusammenhang andiskutiert; der Schwerpunkt liegt allerdings auf den externen Kosten. Im Rahmen der Arbeit werden zunächst Definitionen wesentlicher Terminologien dargestellt, soweit diese für das Verständnis der sich anschließenden Diskussion und Festlegung der Grundlagen der entwickelten Berechnungsmethodik notwendig erscheinen. Diese Diskussion und Festlegung umfasst die Bereiche Kostenrechnungsart, Bewertungsverfahren zur Ermittlung des Wertegerüsts, Diskontrate, zu betrachtende Kostenbereiche, Mengengerüst und Allokationsrechnung. Darauf folgend werden die betrachteten Kostenbereiche anhand vorliegender Studien und eigener Überlegungen detailliert dargestellt und das Wertegerüst bestimmt. Außerdem wird die Allokationsrechnung und das für die Berechnung heranzuziehende Mengengerüst für jeden Bereich separat vorgestellt. Anschließend wird die entwickelte Berechnungsmethodik auf ein Beispielnetz (Autobahnnetz Thüringen) angewendet. Neben der Vorstellung des Untersuchungsgebiets, der Berechnung der externen Kosten und der disaggregierten Ergebnisdarstellung wird die Einteilung des Beispielnetzes in unterschiedliche Preiskategorien auf der Grundlage der abschnittsbezogen vorliegenden Ergebnisse diskutiert, auf deren Basis die externen Kosten über Straßenbenutzungsgebühren internalisiert werden könnten. Im Rahmen einer Sensitivitätsanalyse werden einzelne Annahmen der Berechnungsmethodik bzw. Kostensätze des Wertegerüsts variiert. Die Auswirkungen dieser Variationen werden wiederum am Beispielnetz, für das erneute Kostenberechnungen vorgenommen werden, dargelegt. Abschließend werden offen gebliebene Fragestellungen und Empfehlungen für weitere Untersuchungen benannt.
One of the main focuses of recent Chinese urban development is the creation and retrofitting of public spaces driven by the market force and demand. However, researches concerning human and cultural influences on shaping public spaces have been scanty. There still exist many undefined ambiguous planning aspects institutionally and legislatively. This is an explanatory research to address interactions, incorporations and interrelationship between the lived environment and its peoples. It is knowledge-seeking and normative. Theoretically, public space in a Chinese context is conceptualized; empirically, a selected case is inquired. The research has unfolded a comparatively complete understanding of China’s planning evolution and on-going practices. Data collection emphasizes the concept of ‘people’ and ‘space’. First-hand data is derived from the intensive fieldwork and observatory and participatory documentations. The ample detailed authentic empirical data empowers space syntax as a strong analysis tool in decoding how human’s activities influence the public space. Findings fall into two categories but interdependent. Firstly, it discloses the studied settlement as a generic, organic and incremental development model. Its growth and established environment is evolutionary and incremental, based on its intrinsic traditions, life values and available resources. As a self-sustaining settlement, it highlights certain vernacular traits of spatial development out of lifestyles and cultural practices. Its spatial articulation appears as a process parallel to socio-economic transitions. Secondly, crucial planning aspects are theoretically summarized to address the existing gap between current planning methodology and practicalities. It pinpoints several most significant and particular issues, namely, disintegrated land use system and urban planning; missing of urban design in the planning system, loss of a human-responsive environment resulted from standardized planning and under-estimation of heritage in urban development. The research challenges present Chinese planning laws and regulations through urban public space study; and pinpoints to yield certain growth leverage for planning and development. Thus, planning is able to empower inhabitants to make decisions along the process of shaping and sustaining their space. Therefore, it discusses not only legislative issues, concerning land use planning, urban design and heritage conservation. It leads to a pivotal proposal, i.e., the integration of human and their social spaces in formulating a new spatial strategy. It expects to inform policymakers of underpinning social values and cultural practices in reconfiguring postmodern Chinese spatiality. It propounds that social context endemic to communities shall be integrated as a crucial tool in spatial strategy design, hence to strengthen spatial attributes and improve life quality.
On the mechanisms of shrinkage reducing admixtures in self con-solidating mortars and concretes
(2010)
Self Consolidating Concrete – a dream has come true!(?) Self Consolidating Concrete (SCC) is mainly characterised by its special rheological properties. With-out any vibration this concrete can be placed and compacted under its own weight, without segrega-tion or bleeding. The use of such concrete can increase the productivity on construction sites and en-able the use of a higher degree of well distributed reinforcement for thin walled structural members. This new technology also reduces health risks since in contrast to the traditional handling of concrete, the emission of noise and vibration are substantially decreased. The specific mix design for self consolidating concretes was introduced around the 1980s in Japan. In comparison to normal vibrated concrete an increased paste volume enables a good distribution of aggregates within the paste matrix, minimising the influence of aggregates friction on the concrete flow property. The introduction of inert and/or pozzolanic additives as part of the paste provides the required excess paste volume without using disproportionally high amounts of plain cement. Due to further developments of concrete admixtures such as superplasticizers, the cement paste can gain self levelling properties without causing segregation of aggregates. Whereas SCC differs from normal vibrated concrete in its fresh attributes, it should reach similar properties in the hardened state. Due to the increased paste volume it usually shows higher shrinkage. Furthermore, owing to strength requirements, SCC is often produced at low water to cement ratios and hence may additionally suffer from autogenous shrinkage. This means that cracking caused by drying or autogenous shrinkage is a real risk for SCC and can compromise its durability as cracks may serve as ingression paths for gases and salts or might permit leaching. For the time being SCC still exhibits increased shrinkage and cracking probability and hence may be discarded in many practical applications. This can be overcome by a better understanding of those mechanisms and the ways to mitigate them. It is a target of this thesis to contribute to this. How to cope with increased shrinkage of SCC? In general, engineers are facing severe problems related to shrinkage and cracking. Even for normal and high performance concrete, containing moderate amounts of binder, a lot of effort was put on counteracting shrinkage and avoiding cracking. For the time being these efforts resulted in the knowledge of how to distribute cracks rather to avoid them. The most efficient way to decrease shrinkage turned out to be to decrease the cement content of concrete down to a minimum but still sufficient amount. For SCC this obviously seems to be contradictory with the requirement of a high paste volume. Indeed, the potential for shrinkage reduction is limited to some small range modifications in the mix design following two major concepts. The first one is the reduction of the required paste volume by optimising the aggregate grading curve. The second one involves high volume substitution of cement, preferentially using inert mineral additives. The optimization of grading curves is limited by several severe practical issues. Problems start with the availability of sufficiently fractionated aggregates. Usually attempts fail because of the enormous effort in composing application-optimized grading curves or mix designs. Due to durability reasons, the substitution rate for cement is limited depending on the application purpose and on environmental exposure of the hardened concrete. In the early 1980s Shrinkage Reducing Admixtures (SRA) were introduced to counteract drying shrinkage of concrete. The first publications explicitly dealing with SRA go back to Goto and Sato (Japan). They were published in 1983, which is also the time when the SCC concept was introduced. SRA modified concretes showed a substantial reduction of free drying shrinkage contributing to crack prevention or at least a significant decrease of crack width in situations of restrained drying shrinkage. Will shrinkage reducing admixtures contribute to a broader application of SCC? Within the last three decades performance tests on several types of concrete proved the efficiency of shrinkage reducing admixtures. So, at least in terms of shrinkage and cracking, concretes in general and SCC in particular can benefit from SRA application. But "One man's meat is another man's poison" and with respect to long term performance of SRA modified concretes there are still several issues to be clarified. One of these concerns the impact of SRAs on cement hydration. It is therefore an issue to know if changes in the hydrated phase composition, induced by SRA, result in undesired properties or decreased durability. Another issue is that the long term shrinkage reduction has to be evaluated. For example, one can wonder if SRA leaching may diminish or even eliminate long term shrinkage reduction and if the release of admixtures could be a severe environmental issue. It should also be noted that the basic mechanism or physical impact of SRA as well as its implementation in recent models for shrinkage of concrete is still being discussed. The present thesis tries to shed light on the role of SRA in self consolidating concrete focusing on the three questions outlined above: basic mechanisms of cement hydration, physical impact on shrinkage and the sustainability of SRA-application. Which contributions result from this study? Based on an extensive patent search, commercial SRAs could be identified to be synergistic mixtures of non-ionic surfactants and glycols. This turns out to be most important information for more than one reason and is the subject of chapter 4. An abundant literature focuses on properties of these non-ionic surfactants. Moreover, from this rich pool of information, the behaviour of SRAs and their interactions in cementitious systems were better understood through this thesis. For example, it could be anticipated how SRAs behave in strong electrolytes and how surface activity, i.e. surface tension, and interparticle forces might be affected. The synergy effect regarding enhanced performance induced by the presence of additional glycol in SRAs could be derived from the literature on the co-surfactant nature of glycols. Generally it now can be said that glycols ensure that the non-ionic surfactant is properly distributed onto the paste interfaces to efficiently reduce surface tension. In literature, the impact of organic matter on cement hydration was extensively studied for other admixtures like superplasticizer. From there, main impact factors related to the nature of these molecules could be identified. In addition, here again, the literature on non-ionic surfactants provides sufficient information to anticipate possible interactions of SRA with cement hydration based on the nature of non-ionic surfactants. All in all, the extensive study on the nature of non-ionic surfactants, presented in chapter 4, provides fundamental understanding of the behaviour of SRAs in cement paste. Taking a step further to relate this to the impact on drying and shrinkage required to review recent models for drying and shrinkage of cement paste as presented in chapter 3. There, it is shown that macroscopic thermodynamics of the open pore systems can be successfully applied to predict drying induced deformation, but that surface activity of SRA still has to be implemented to explain the shrinkage reduction it causes. Because of severe issues concerning the importance of capillary pressure on shrinkage, a new macroscopic thermodynamic model was derived in a way that meets requirements to properly incorporate surface activity of SRA. This is the subject of chapter 5. Based on theoretical considerations, in chapter 5 the broader impact of SRA on drying cementitious matter could be outlined. In a next step, cement paste was treated as a deformable, open drying pore system. Thereby, the drying phenomena of SRA modified mortars and concrete observed by other authors could be retrieved. This phenomenological consistency of the model constitutes an important contribution towards the understanding of SRA mechanisms. Another main contribution of this work came from introducing an artificial pore system, denominated the normcube. Using this model system, it could be shown how the evolution of interfacial area and its properties interact in presence of SRAs and how this impacts drying characteristics. In chapter 7, the surface activity of commercial SRAs in aqueous solution and synthetic pore solution was investigated. This shows how the electrolyte concentration of synthetic pore solution impacts the phase behaviour of SRA and conversely, how the presence of SRA impacts the aqueous electrolyte solution. Whilst electrolytes enhance self-aggregation of SRAs into micelles and liquid crystals, the presence of SRAs leads to precipitation of minerals as syngenite and mirabilite. Moreover, electrolyte solutions containing SRAs comprise limited miscibility or rather show miscibility gaps, where the liquid separates into isotropic micellar solutions and surfactant rich reverse micellar solutions. The investigation of surface activity and phase behaviour of SRA unravelled another important contribution. From macroscopic surface tension measurements, a relationship between excess surface concentration of SRA, bulk concentration of SRA and exposed interfacial area could be derived. Based on this, it is now possible to predict the actual surface tension of the pore fluid in the course of drying once the evolution of internal interfacial area is known. This is used later in this thesis to describe the specific drying and shrinkage behaviour of SRA modified pastes and mortars. Calorimetric studies on normal Portland cement and composite binders revealed that SRA alone show only minor impact on hydration kinetics. In presence of superplasticizer however the cement hydration can be significantly decelerated. The delaying impact of SRA could be related to a selective deceleration of silicate phase hydration. Moreover, it could be shown that portlandite precipitation in presence of SRA is changed, turning the compact habitus into more or less layered structures. Thereby, the specific surface increases, causing the amount of physically bound water to increase, which in turn reduces the maximum degree of hydration achievable for sealed systems. Extensive phase analysis shows that the hydrated phase composition of SRA modified binders re-mains almost unaffected. The appearance of a temporary mineral phase could be detected by environmental scanning electron microscopy. As could be shown for synthetic pore solutions, syngenite precipitates during early hydration stages and is later consumed in the course of aluminate hydration, i.e. when sulphates are depleted. Moreover, for some SRAs, the salting out phenomena supposed to be enhanced in strong electrolytes could also be shown to take place. The resulting organic precipitates could be identified by SEM-EDX in cement paste and by X-ray diffraction on solid residues of synthetic pore solution. The presence of SRAs could also be identified to impact microstructure of well cured cement paste. Based on nitrogen adsorption measurements and mercury intrusion porosimetry the amount of small pores is seen to increase with SRA dosage, whilst the overall porosity remains unchanged. The question regarding sustainability of SRA application is the subject of chapter 10. By means of leaching studies it could be shown that SRA can be leached significantly. The mechanism could be identified as a diffusion process and a range of effective diffusion coefficients could be estimated. Thereby, the leaching of SRA can now be estimated for real structural members. However, while the admixture can be leached to high extents in tank tests, the leaching rates in practical applications can be assumed to be low because of much reduced contact with water. This could be proven by quantifying admixture loss during long term drying and rewetting cycles. Despite a loss of admixture shrinkage reduction is hardly impacted. Moreover, the cyclic tests revealed that the total deformations in presence of SRA remain low due to a lower extent of irreversibly shrinkage deformations. Another important contribution towards the better understanding of the working mechanism of SRA for drying and shrinkage came from the same leaching tests. A significant fraction of SRA is found to be immobile and does not diffuse in leaching. This fraction of SRA is probably strongly associated to cement phases as the calcium-silicate-hydrates or portlandite. Based on these findings, it is now also possible to quantify the amount of admixture active at the interfaces. This means that, the evolution of surface tension in the course of drying can be approximated, which is a fundamental requirement for modeling shrinkage in presence of SRA. The last experimental chapter of this study focuses on the working mechanism and impact of SRA on drying and shrinkage. Based on the thermodynamics of the open deformable pore system introduced in chapter 5, energy balances are set up using desorption and shrinkage isotherms of actual samples. Information on distribution of SRA in the hydrated paste is used to estimate the actual surface tensions of the pore solution. In other words, this is the first time that the surface activity of the SRA in the course of the drying is fully accounted for. From the energy balances the evolution and properties of the internal interface are then obtained. This made it possible to explain why SRAs impact drying and shrinkage and in what specific range of relative humidity they are active. Summarising the findings of this thesis it can be said that the understanding of the impact of SRAs on hydration, drying and shrinkage was brought forward. Many of the new insights came from the careful investigation of the theory of non-ionic surfactants, something that the cement community had generally overlooked up to now.