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This article is focused on the research and development of new cellulose ether derivatives as innovative superplasticizers for mortar systems. Several synthetic strategies have been pursued to obtain new compounds to study their properties on cementitious systems as new bio-based additives. The new water-soluble admixtures were synthesized using a complex carboxymethylcellulose-based backbone that was first hydrolyzed and then sulfo-ethylated in the presence of sodium vinyl sulphonate. Starting with a complex biopolymer that is widely known as a thickening agent was very challenging. Only by varying the hydrolysis times and temperatures of the reactions was achieved the aimed goal. The obtained derivatives showed different molecular weight (Mw) and anionic charges on their backbones. An improvement in shear stress and dynamic viscosity values of CEM II 42.5R cement was observed with the samples obtained with a longer time of higher temperature hydrolysis and sulfo-ethylation. Investigations into the chemical nature of the pore solution, calorimetric studies and adsorption experiments clearly showed the ability of carboxymethyl cellulose superplasticizer (CMC SP) to interact with cement grains and influence hydration processes within a 48-h time window, causing a delay in hydration reactions in the samples. The fluidity of the cementitious matrices was ascertained through slump test and preliminary studies of mechanical and flexural strength of the hardened mortar formulated with the new ecological additives yielded values in terms of mechanical properties. Finally, the computed tomography (CT) images completed the investigation of the pore network structure of hardened specimens, highlighting their promising structure porosity.
Biofeedback constitutes a well-established, non-invasive method to voluntary interfere in emotional processing by means of cognitive strategies. However, treatment durations exhibit strong inter-individual variations and first successes can often be achieved only after a large number of sessions. Sham feedback constitutes a rather untapped approach by providing feedback that does not correspond to the participant’s actual state. The current study aims to gain insights into mechanisms of sham feedback processing in order to support new techniques in biofeedback therapy. We carried out two experiments and applied different types of sham feedback on skin conductance responses and pupil size changes during affective processing. Results indicate that standardized but context-sensitive sham signals based on skin conductance responses exert a stronger influence on emotional regulation compared to individual sham feedback from ongoing pupil dynamics. Also, sham feedback should forego unnatural signal behavior to avoid irritation and skepticism among participants. Altogether, a reasonable combination of stimulus features and sham feedback characteristics enables to considerably reduce the actual bodily responsiveness already within a single session.
Stadtpolitik für alle
(2021)
Die Corona-Krise hat die Erosion städtischer Solidarität offen zu Tage treten lassen. Dagegen bringen Anton Brokow-Loga und Frank Eckardt in dieser Schrift die praktische Utopie einer solidarischen Postwachstumsstadt „auf den Punkt“.
Vom Commoning über die Umverteilung der städtischen Flächen bis zu einer sozial-ökologischen Verkehrswende: Eine progressive Stadtpolitik für alle überwindet bisheriges Schubladendenken. Sie setzt stattdessen auf heterogene Zusammenhänge und ungewöhnliche Bündnisse. Zu dem hier umrissenen Vorhaben gehört auch, eine basisdemokratisch orientierte Stadtpolitik mit dem Ziel einer umfassenden Transformation von Stadt und Gesellschaft zu verknüpfen.
Wie kann ein Blick auf die kommunale Ebene helfen, globalen Ungerechtigkeiten zu begegnen? Welchen Weg weisen munizipalistische Plattformen und Vergemeinschaftungen jenseits von Privat- oder Staatseigentum?