TY - JOUR A1 - Mehling, Simon A1 - Schnabel, Tobias A1 - Londong, Jörg T1 - Photocatalytic ozonation in an immersion rotary body reactor for the removal of micro-pollutants from the effluent of wastewater treatment plants JF - Water Science & Technology N2 - Carrier-bound titanium dioxide catalysts were used in a photocatalytic ozonation reactor for the degradation of micro-pollutants in real wastewater. A photocatalytic immersion rotary body reactor with a 36-cm disk diameter was used, and was irradiated using UV-A light-emitting diodes. The rotating disks were covered with catalysts based on stainless steel grids coated with titanium dioxide. The dosing of ozone was carried out through the liquid phase via an external enrichment and a supply system transverse to the flow direction. The influence of irradiation power and ozone dose on the degradation rate for photocatalytic ozonation was investigated. In addition, the performance of the individual processes photocatalysis and ozonation were studied. The degradation kinetics of the parent compounds were determined using liquid chromatography tandem mass spectrometry. First-order kinetics were determined for photocatalysis and photocatalytic ozonation. A maximum reaction rate of the reactor was determined, which could be achieved by both photocatalysis and photocatalytic ozonation. At a dosage of 0.4 mg /mg DOC, the maximum reaction rate could be achieved using 75% of the irradiation power used for sole photocatalysis, allowing increases in the energetic efficiency of photocatalytic wastewater treatment processes. The process of photocatalytic ozonation is suitable to remove a wide spectrum of micro-pollutants from wastewater. KW - Abwasserreinigung KW - Fotokatalyse KW - Mikroverunreinigungen KW - anthropogenic micro-pollutants KW - photocatalysis KW - photocatalytic ozonation KW - wastewater treatment KW - titan dioxide Y1 - 2021 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:gbv:wim2-20220209-45865 UR - https://iwaponline.com/wst/article/85/1/535/85800/Photocatalytic-ozonation-in-an-immersion-rotary VL - 2022 IS - volume 85, issue 1 SP - 535 EP - 548 PB - IWA Publishing CY - London ER - TY - JOUR A1 - Mehling, Simon A1 - Schnabel, Tobias A1 - Londong, Jörg T1 - Investigation on Energetic Efficiency of Reactor Systems for Oxidation of Micro-Pollutants by Immobilized Active Titanium Dioxide Photocatalysis JF - Water N2 - In this work, the degradation performance for the photocatalytic oxidation of eight micropollutants (amisulpride, benzotriazole, candesartan, carbamazepine, diclofenac, gabapentin, methlybenzotriazole, and metoprolol) within real secondary effluent was investigated using three different reactor designs. For all reactor types, the influence of irradiation power on its reaction rate and energetic efficiency was investigated. Flat cell and batch reactor showed almost similar substance specific degradation behavior. Within the immersion rotary body reactor, benzotriazole and methylbenzotriazole showed a significantly lower degradation affinity. The flat cell reactor achieved the highest mean degradation rate, with half time values ranging from 5 to 64 min with a mean of 18 min, due to its high catalysts surface to hydraulic volume ratio. The EE/O values were calculated for all micro-pollutants as well as the mean degradation rate constant of each experimental step. The lowest substance specific energy per order (EE/O) values of 5 kWh/m3 were measured for benzotriazole within the batch reactor. The batch reactor also reached the lowest mean values (11.8–15.9 kWh/m3) followed by the flat cell reactor (21.0–37.0 kWh/m3) and immersion rotary body reactor (23.9–41.0 kWh/m3). Catalyst arrangement and irradiation power were identified as major influences on the energetic performance of the reactors. Low radiation intensities as well as the use of submerged catalyst arrangement allowed a reduction in energy demand by a factor of 3–4. A treatment according to existing treatment goals of wastewater treatment plants (80% total degradation) was achieved using the batch reactor with a calculated energy demand of 7000 Wh/m3. KW - Fotokatalyse KW - Abwasserreinigung KW - photocatalysis KW - micro-pollutant treatment KW - titanium dioxid KW - reactor design KW - energy per order KW - OA-Publikationsfonds2022 Y1 - 2022 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:gbv:wim2-20220912-47130 UR - https://www.mdpi.com/2073-4441/14/17/2681 VL - 2022 IS - Volume 14, issue 7, article 2681 SP - 1 EP - 15 PB - MDPI CY - Basel ER -