TY - JOUR A1 - Mehling, Simon A1 - Schnabel, Tobias A1 - Londong, Jörg T1 - Investigation on Energetic Efficiency of Reactor Systems for Oxidation of Micro-Pollutants by Immobilized Active Titanium Dioxide Photocatalysis JF - Water N2 - In this work, the degradation performance for the photocatalytic oxidation of eight micropollutants (amisulpride, benzotriazole, candesartan, carbamazepine, diclofenac, gabapentin, methlybenzotriazole, and metoprolol) within real secondary effluent was investigated using three different reactor designs. For all reactor types, the influence of irradiation power on its reaction rate and energetic efficiency was investigated. Flat cell and batch reactor showed almost similar substance specific degradation behavior. Within the immersion rotary body reactor, benzotriazole and methylbenzotriazole showed a significantly lower degradation affinity. The flat cell reactor achieved the highest mean degradation rate, with half time values ranging from 5 to 64 min with a mean of 18 min, due to its high catalysts surface to hydraulic volume ratio. The EE/O values were calculated for all micro-pollutants as well as the mean degradation rate constant of each experimental step. The lowest substance specific energy per order (EE/O) values of 5 kWh/m3 were measured for benzotriazole within the batch reactor. The batch reactor also reached the lowest mean values (11.8–15.9 kWh/m3) followed by the flat cell reactor (21.0–37.0 kWh/m3) and immersion rotary body reactor (23.9–41.0 kWh/m3). Catalyst arrangement and irradiation power were identified as major influences on the energetic performance of the reactors. Low radiation intensities as well as the use of submerged catalyst arrangement allowed a reduction in energy demand by a factor of 3–4. A treatment according to existing treatment goals of wastewater treatment plants (80% total degradation) was achieved using the batch reactor with a calculated energy demand of 7000 Wh/m3. KW - Fotokatalyse KW - Abwasserreinigung KW - photocatalysis KW - micro-pollutant treatment KW - titanium dioxid KW - reactor design KW - energy per order KW - OA-Publikationsfonds2022 Y1 - 2022 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:gbv:wim2-20220912-47130 UR - https://www.mdpi.com/2073-4441/14/17/2681 VL - 2022 IS - Volume 14, issue 7, article 2681 SP - 1 EP - 15 PB - MDPI CY - Basel ER - TY - JOUR A1 - Aicher, Andreas A1 - Börmel, Melanie A1 - Londong, Jörg A1 - Beier, Silvio T1 - Vertical green system for gray water treatment: Analysis of the VertiKKA-module in a field test JF - Frontiers in Environmental Science N2 - This work presents a modular Vertical Green System (VGS) for gray water treatment, developed at the Bauhaus-Universität Weimar. The concept was transformed into a field study with four modules built and tested with synthetic gray water. Each module set contains a small and larger module with the same treatment substrate and was fed hourly. A combination of lightweight structural material and biochar of agricultural residues and wood chips was used as the treatment substrate. In this article, we present the first 18 weeks of operation. Regarding the treatment efficiency, the parameters chemical oxygen demand (COD), total phosphorous (TP), ortho-phosphate (ortho-P), total bound nitrogen (TNb), ammonium nitrogen (NH4-N), and nitrate nitrogen (NO3-N) were analyzed and are presented in this work. The results of the modules with agricultural residues are promising. Up to 92% COD reduction is stated in the data. The phosphate and nitrogen fractions are reduced significantly in these modules. By contrast, the modules with wood chips reduce only 67% of the incoming COD and respectively less regarding phosphates and the nitrogen fraction. KW - Grauwasser KW - Abwassertechnologie KW - vertical green system KW - grey water treatment KW - urban heat island effect KW - OA-Publikationsfonds2022 Y1 - 2022 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:gbv:wim2-20230124-48840 UR - https://www.frontiersin.org/articles/10.3389/fenvs.2022.976005/full VL - 2022 IS - Volume 10 (2022), article 976005 SP - 1 EP - 7 PB - Frontiers Media CY - Lausanne ER -