@article{ZhaoLuZhangetal.,
  author    = {Zhao, Jun-Hua and Lu, Lixin and Zhang, Zhiliang and Guo, Wanlin and Rabczuk, Timon},
  title     = {Continuum modeling of the cohesive energy for the interfaces between _lms, spheres, coats and substrates},
  series = {Computational Materials Science},
  journal   = {Computational Materials Science},
  pages     = {432 -- 438},
  abstract  = {Continuum modeling of the cohesive energy for the interfaces between _lms, spheres, coats and substrates},
  subject      = {Angewandte Mathematik},
  language  = {en}
}
@article{ZhaoJiaWeietal.,
  author    = {Zhao, Jun-Hua and Jia, Yue and Wei, Ning and Rabczuk, Timon},
  title     = {Binding energy and mechanical stability of two parallel and crossing carbon nanotubes},
  series = {Journal of Applied Mechanics},
  journal   = {Journal of Applied Mechanics},
  abstract  = {Binding energy and mechanical stability of two parallel and crossing carbon nanotubes},
  subject      = {Angewandte Mathematik},
  language  = {en}
}
@article{ZhaoLuRabczuk,
  author    = {Zhao, Jiyun and Lu, Lixin and Rabczuk, Timon},
  title     = {The tensile and shear failure behavior dependence on chain length and temperature in amorphous polymers},
  series = {Computational Materials Science},
  journal   = {Computational Materials Science},
  pages     = {567 -- 572},
  abstract  = {The tensile and shear failure behavior dependence on chain length and temperature in amorphous polymers},
  subject      = {Angewandte Mathematik},
  language  = {en}
}
@article{YangBudarapuMahapatraetal.,
  author    = {Yang, Shih-Wei and Budarapu, Pattabhi Ramaiah and Mahapatra, D.R. and Bordas, St{\´e}phane Pierre Alain and Zi, Goangseup and Rabczuk, Timon},
  title     = {A Meshless Adaptive Multiscale Method for Fracture},
  series = {Computational Materials Science},
  journal   = {Computational Materials Science},
  pages     = {382 -- 395},
  abstract  = {A Meshless Adaptive Multiscale Method for Fracture},
  subject      = {Angewandte Mathematik},
  language  = {en}
}
@inproceedings{WiggenbrockSmarsly,
  author    = {Wiggenbrock, Jens and Smarsly, Kay},
  title     = {A GENERIC FRAMEWORK SUPPORTING DISTRIBUTED COMPUTING IN ENGINEERING APPLICATIONS},
  series = {Digital Proceedings, International Conference on the Applications of Computer Science and Mathematics in Architecture and Civil Engineering : July 20 - 22 2015, Bauhaus-University Weimar},
  booktitle = {Digital Proceedings, International Conference on the Applications of Computer Science and Mathematics in Architecture and Civil Engineering : July 20 - 22 2015, Bauhaus-University Weimar},
  editor    = {G{\"u}rlebeck, Klaus and Lahmer, Tom},
  organization    = {Bauhaus-Universit{\"a}t Weimar},
  issn      = {1611-4086},
  doi       = {10.25643/bauhaus-universitaet.2826},
  url       = {http://nbn-resolving.de/urn:nbn:de:gbv:wim2-20170314-28260},
  pages     = {9},
  abstract  = {Modern distributed engineering applications are based on complex systems consisting of various subsystems that are connected through the Internet. Communication and collaboration within an entire system requires reliable and efficient data exchange between the subsystems. Middleware developed within the web evolution during the past years provides reliable and efficient data exchange for web applications, which can be adopted for solving the data exchange problems in distributed engineering applications. This paper presents a generic approach for reliable and efficient data exchange between engineering devices using existing middleware known from web applications. Different existing middleware is examined with respect to the suitability in engineering applications. In this paper, a suitable middleware is shown and a prototype implementation simulating distributed wind farm control is presented and validated using several performance measurements.},
  subject      = {Angewandte Informatik},
  language  = {en}
}
@article{WangArash,
  author    = {Wang, Quan and Arash, Behrouz},
  title     = {Announcement of a virtual special issue on computational carbon nanoscience},
  series = {Carbon},
  journal   = {Carbon},
  doi       = {10.1016/j.carbon.2015.05.082},
  url       = {http://nbn-resolving.de/urn:nbn:de:gbv:wim2-20170428-31695},
  pages     = {370 -- 372},
  abstract  = {The Carbon journal is pleased to introduce a themed collection of recent articles in the area of computational carbon nanoscience. This virtual special issue was assembled from previously published Carbon articles by Guest Editors Quan Wang and Behrouz Arash, and can be accessed as a set in the special issue section of the journal website homepage: www.journals.elsevier.com/carbon. The article below by our guest editors serves as an introduction to this virtual special issue, and also a commentary on the growing role of computation as a tool to understand the synthesis and properties of carbon nanoforms and their behavior in composite materials.},
  subject      = {Kohlenstoff},
  language  = {en}
}
@article{VuBacSilaniLahmeretal.,
  author    = {Vu-Bac, N. and Silani, Mohammad and Lahmer, Tom and Zhuang, Xiaoying and Rabczuk, Timon},
  title     = {A unified framework for stochastic predictions of Young's modulus of clay/epoxy nanocomposites (PCNs)},
  series = {Computational Materials Science},
  journal   = {Computational Materials Science},
  pages     = {520 -- 535},
  abstract  = {A unified framework for stochastic predictions of Young's modulus of clay/epoxy nanocomposites (PCNs)},
  subject      = {Angewandte Mathematik},
  language  = {en}
}
@article{VuBacRafieeZhuangetal.,
  author    = {Vu-Bac, N. and Rafiee, Roham and Zhuang, Xiaoying and Lahmer, Tom and Rabczuk, Timon},
  title     = {Uncertainty quantification for multiscale modeling of polymer nanocomposites with correlated parameters},
  series = {Composites Part B: Engineering},
  journal   = {Composites Part B: Engineering},
  pages     = {446 -- 464},
  abstract  = {Uncertainty quantification for multiscale modeling of polymer nanocomposites with correlated parameters},
  subject      = {Angewandte Mathematik},
  language  = {en}
}
@phdthesis{Vu,
  author    = {Vu, Bac Nam},
  title     = {Stochastic uncertainty quantification for multiscale modeling of polymeric nanocomposites},
  doi       = {10.25643/bauhaus-universitaet.2555},
  url       = {http://nbn-resolving.de/urn:nbn:de:gbv:wim2-20160322-25551},
  school      = {Bauhaus-Universit{\"a}t Weimar},
  pages     = {265},
  abstract  = {Nanostructured materials are extensively applied in many fields of material science for new industrial applications, particularly in the automotive, aerospace industry due to their exceptional physical and mechanical properties. Experimental testing of nanomaterials is expensive, timeconsuming,challenging and sometimes unfeasible. Therefore,computational simulations have been employed as alternative method to predict macroscopic material properties. The behavior of polymeric nanocomposites (PNCs) are highly complex. The origins of macroscopic material properties reside in the properties and interactions taking place on finer scales. It is therefore essential to use multiscale modeling strategy to properly account for all large length and time scales associated with these material systems, which across many orders of magnitude. Numerous multiscale models of PNCs have been established, however, most of them connect only two scales. There are a few multiscale models for PNCs bridging four length scales (nano-, micro-, meso- and macro-scales). In addition, nanomaterials are stochastic in nature and the prediction of macroscopic mechanical properties are influenced by many factors such as fine-scale features. The predicted mechanical properties obtained by traditional approaches significantly deviate from the measured values in experiments due to neglecting uncertainty of material features. This discrepancy is indicated that the effective macroscopic properties of materials are highly sensitive to various sources of uncertainty, such as loading and boundary conditions and material characteristics, etc., while very few stochastic multiscale models for PNCs have been developed. Therefore, it is essential to construct PNC models within the framework of stochastic modeling and quantify the stochastic effect of the input parameters on the macroscopic mechanical properties of those materials. This study aims to develop computational models at four length scales (nano-, micro-, meso- and macro-scales) and hierarchical upscaling approaches bridging length scales from nano- to macro-scales. A framework for uncertainty quantification (UQ) applied to predict the mechanical properties of the PNCs in dependence of material features at different scales is studied. Sensitivity and uncertainty analysis are of great helps in quantifying the effect of input parameters, considering both main and interaction effects, on the mechanical properties of the PNCs. To achieve this major goal, the following tasks are carried out: At nano-scale, molecular dynamics (MD) were used to investigate deformation mechanism of glassy amorphous polyethylene (PE) in dependence of temperature and strain rate. Steered molecular dynamics (SMD)were also employed to investigate interfacial characteristic of the PNCs. At mico-scale, we developed an atomistic-based continuum model represented by a representative volume element (RVE) in which the SWNT's properties and the SWNT/polymer interphase are modeled at nano-scale, the surrounding polymer matrix is modeled by solid elements. Then, a two-parameter model was employed at meso-scale. A hierarchical multiscale approach has been developed to obtain the structure-property relations at one length scale and transfer the effect to the higher length scales. In particular, we homogenized the RVE into an equivalent fiber. The equivalent fiber was then employed in a micromechanical analysis (i.e. Mori-Tanaka model) to predict the effective macroscopic properties of the PNC. Furthermore, an averaging homogenization process was also used to obtain the effective stiffness of the PCN at meso-scale. Stochastic modeling and uncertainty quantification consist of the following ingredients: - Simple random sampling, Latin hypercube sampling, Sobol' quasirandom sequences, Iman and Conover's method (inducing correlation in Latin hypercube sampling) are employed to generate independent and dependent sample data, respectively. - Surrogate models, such as polynomial regression, moving least squares (MLS), hybrid method combining polynomial regression and MLS, Kriging regression, and penalized spline regression, are employed as an approximation of a mechanical model. The advantage of the surrogate models is the high computational efficiency and robust as they can be constructed from a limited amount of available data. - Global sensitivity analysis (SA) methods, such as variance-based methods for models with independent and dependent input parameters, Fourier-based techniques for performing variance-based methods and partial derivatives, elementary effects in the context of local SA, are used to quantify the effects of input parameters and their interactions on the mechanical properties of the PNCs. A bootstrap technique is used to assess the robustness of the global SA methods with respect to their performance. In addition, the probability distribution of mechanical properties are determined by using the probability plot method. The upper and lower bounds of the predicted Young's modulus according to 95 \% prediction intervals were provided. The above-mentioned methods study on the behaviour of intact materials. Novel numerical methods such as a node-based smoothed extended finite element method (NS-XFEM) and an edge-based smoothed phantom node method (ES-Phantom node) were developed for fracture problems. These methods can be used to account for crack at macro-scale for future works. The predicted mechanical properties were validated and verified. They show good agreement with previous experimental and simulations results.},
  subject      = {Polymere},
  language  = {en}
}
@inproceedings{VolkovKirschkeChelyshkovetal.,
  author    = {Volkov, Andrey and Kirschke, Heiko and Chelyshkov, Pavel and Sedov, Artem and Lysenko, Denis},
  title     = {THE CRITERIA'S SET WITH INVARIANT DESIGN BUILDING ELEMENTS ON THE BASE OF THREE IMPUTATIONS: "CONVENIENCE", "SAFETY" AND "ENERGY-EFFICIENCY"},
  series = {Digital Proceedings, International Conference on the Applications of Computer Science and Mathematics in Architecture and Civil Engineering : July 20 - 22 2015, Bauhaus-University Weimar},
  booktitle = {Digital Proceedings, International Conference on the Applications of Computer Science and Mathematics in Architecture and Civil Engineering : July 20 - 22 2015, Bauhaus-University Weimar},
  editor    = {G{\"u}rlebeck, Klaus and Lahmer, Tom},
  organization    = {Bauhaus-Universit{\"a}t Weimar},
  issn      = {1611-4086},
  doi       = {10.25643/bauhaus-universitaet.2795},
  url       = {http://nbn-resolving.de/urn:nbn:de:gbv:wim2-20170314-27956},
  pages     = {6},
  abstract  = {The paper deals with the formalization of the criteria for constructing building management systems. We consider three criteria - "convenience", "safety" and "energyefficiency". For each objective proposed method of calculation.},
  subject      = {Angewandte Informatik},
  language  = {en}
}
@inproceedings{Vieira,
  author    = {Vieira, Nelson},
  title     = {SOME RESULTS IN FRACTIONAL CLIFFORD ANALYSIS},
  series = {Digital Proceedings, International Conference on the Applications of Computer Science and Mathematics in Architecture and Civil Engineering : July 20 - 22 2015, Bauhaus-University Weimar},
  booktitle = {Digital Proceedings, International Conference on the Applications of Computer Science and Mathematics in Architecture and Civil Engineering : July 20 - 22 2015, Bauhaus-University Weimar},
  editor    = {G{\"u}rlebeck, Klaus and Lahmer, Tom},
  organization    = {Bauhaus-Universit{\"a}t Weimar},
  issn      = {1611-4086},
  doi       = {10.25643/bauhaus-universitaet.2825},
  url       = {http://nbn-resolving.de/urn:nbn:de:gbv:wim2-20170314-28256},
  pages     = {6},
  abstract  = {What is nowadays called (classic) Clifford analysis consists in the establishment of a function theory for functions belonging to the kernel of the Dirac operator. While such functions can very well describe problems of a particle with internal SU(2)-symmetries, higher order symmetries are beyond this theory. Although many modifications (such as Yang-Mills theory) were suggested over the years they could not address the principal problem, the need of a n-fold factorization of the d'Alembert operator. In this paper we present the basic tools of a fractional function theory in higher dimensions, for the transport operator (alpha = 1/2 ), by means of a fractional correspondence to the Weyl relations via fractional Riemann-Liouville derivatives. A Fischer decomposition, fractional Euler and Gamma operators, monogenic projection, and basic fractional homogeneous powers are constructed.},
  subject      = {Angewandte Informatik},
  language  = {en}
}
@inproceedings{Vasileva,
  author    = {Vasileva, Iuliia},
  title     = {THE PROBLEM OF PARTIAL REINFORCING AN INTERFACE CRACK EDGE BY A RIGID PATCH PLATE UNDER IN-PLANE AND ANTIPLANE LOADS},
  series = {Digital Proceedings, International Conference on the Applications of Computer Science and Mathematics in Architecture and Civil Engineering : July 20 - 22 2015, Bauhaus-University Weimar},
  booktitle = {Digital Proceedings, International Conference on the Applications of Computer Science and Mathematics in Architecture and Civil Engineering : July 20 - 22 2015, Bauhaus-University Weimar},
  editor    = {G{\"u}rlebeck, Klaus and Lahmer, Tom},
  organization    = {Bauhaus-Universit{\"a}t Weimar},
  issn      = {1611-4086},
  doi       = {10.25643/bauhaus-universitaet.2824},
  url       = {http://nbn-resolving.de/urn:nbn:de:gbv:wim2-20170314-28242},
  pages     = {5},
  abstract  = {The stress state of a piecewise-homogeneous elastic body, which has a semi-infinite crack along the interface, under in-plane and antiplane loads is considered. One of the crack edges is reinforced by a rigid patch plate on a finite interval adjacent to the crack tip. The crack edges are loaded with specified stresses. The body is stretched at infinity by specified stresses. External forces with a given principal vector and moment act on the patch plate. The problem reduces to a Riemann-Hilbert boundary-value matrix problem with a piecewise-constant coefficient for two complex potentials in the plane case and for one in the antiplane case. The complex potentials are found explicitly using a Gaussian hypergeometric function. The stress state of the body close to the ends of the patch plate, one of which is also simultaneously the crack tip, is investigated. Stress intensity factors near the singular points are determined.},
  subject      = {Angewandte Informatik},
  language  = {en}
}
@inproceedings{TreyerKleinKoenigetal.,
  author    = {Treyer, Lukas and Klein, Bernhard and K{\"o}nig, Reinhard and Meixner, Christine},
  title     = {Lightweight urban computation interchange (LUCI) system},
  series = {Proceedings},
  booktitle = {Proceedings},
  publisher = {FOSS4G},
  address   = {Seoul, South Korea},
  doi       = {10.25643/bauhaus-universitaet.2598},
  url       = {http://nbn-resolving.de/urn:nbn:de:gbv:wim2-20160622-25982},
  pages     = {12},
  abstract  = {In this paper we introduce LUCI, a Lightweight Urban Calculation Interchange system, designed to bring the advantages of a calculation and content co-ordination system to small planning and design groups by the means of an open source middle-ware. The middle-ware focuses on problems typical to urban planning and therefore features a geo-data repository as well as a job runtime administration, to coordinate simulation models and its multiple views. The described system architecture is accompanied by two exemplary use cases that have been used to test and further develop our concepts and implementations.},
  language  = {en}
}
@inproceedings{TreyerKleinKoenigetal.,
  author    = {Treyer, Lukas and Klein, Bernhard and K{\"o}nig, Reinhard and Meixner, Christine},
  title     = {Lightweight urban computation interchange (LUCI) system},
  series = {FOSS4G 2015 Conference},
  booktitle = {FOSS4G 2015 Conference},
  publisher = {FOSS4G},
  address   = {Seoul, South Korea},
  doi       = {10.25643/bauhaus-universitaet.2504},
  url       = {http://nbn-resolving.de/urn:nbn:de:gbv:wim2-20160118-25042},
  pages     = {12},
  abstract  = {In this paper we introduce LUCI, a Lightweight Urban Calculation Interchange system, designed to bring the advantages of a calculation and content co-ordination system to small planning and design groups by the means of an open source middle-ware. The middle-ware focuses on problems typical to urban planning and therefore features a geo-data repository as well as a job runtime administration, to coordinate simulation models and its multiple views. The described system architecture is accompanied by two exemplary use cases that have been used to test and further develop our concepts and implementations.},
  subject      = {Architektur},
  language  = {en}
}
@article{ThaiNguyenXuanBordasetal.,
  author    = {Thai, Chien H. and Nguyen-Xuan, Hung and Bordas, St{\´e}phane Pierre Alain and Nguyen-Thanh, Nhon and Rabczuk, Timon},
  title     = {Isogeometric analysis of laminated composite plates using the higher-order shear deformation theory},
  series = {Mechanics of Advanced Materials and Structures},
  journal   = {Mechanics of Advanced Materials and Structures},
  pages     = {451 -- 469},
  abstract  = {Isogeometric analysis of laminated composite plates using the higher-order shear deformation theory},
  subject      = {Angewandte Mathematik},
  language  = {en}
}
@inproceedings{TanLahmerSiddappa,
  author    = {Tan, Fengjie and Lahmer, Tom and Siddappa, Manju Gyaraganahalll},
  title     = {SECTION OPTIMIZATION AND RELIABILITY ANALYSIS OF ARCH-TYPE DAMS INCLUDING COUPLED MECHANICAL-THERMAL AND HYDRAULIC FIELDS},
  series = {Digital Proceedings, International Conference on the Applications of Computer Science and Mathematics in Architecture and Civil Engineering : July 20 - 22 2015, Bauhaus-University Weimar},
  booktitle = {Digital Proceedings, International Conference on the Applications of Computer Science and Mathematics in Architecture and Civil Engineering : July 20 - 22 2015, Bauhaus-University Weimar},
  editor    = {G{\"u}rlebeck, Klaus and Lahmer, Tom},
  organization    = {Bauhaus-Universit{\"a}t Weimar},
  issn      = {1611-4086},
  doi       = {10.25643/bauhaus-universitaet.2821},
  url       = {http://nbn-resolving.de/urn:nbn:de:gbv:wim2-20170314-28212},
  pages     = {8},
  abstract  = {From the design experiences of arch dams in the past, it has significant practical value to carry out the shape optimization of arch dams, which can fully make use of material characteristics and reduce the cost of constructions. Suitable variables need to be chosen to formulate the objective function, e.g. to minimize the total volume of the arch dam. Additionally a series of constraints are derived and a reasonable and convenient penalty function has been formed, which can easily enforce the characteristics of constraints and optimal design. For the optimization method, a Genetic Algorithm is adopted to perform a global search. Simultaneously, ANSYS is used to do the mechanical analysis under the coupling of thermal and hydraulic loads. One of the constraints of the newly designed dam is to fulfill requirements on the structural safety. Therefore, a reliability analysis is applied to offer a good decision supporting for matters concerning predictions of both safety and service life of the arch dam. By this, the key factors which would influence the stability and safety of arch dam significantly can be acquired, and supply a good way to take preventive measures to prolong ate the service life of an arch dam and enhances the safety of structure.},
  subject      = {Angewandte Informatik},
  language  = {en}
}
@article{TalebiSilaniRabczuk,
  author    = {Talebi, Hossein and Silani, Mohammad and Rabczuk, Timon},
  title     = {Concurrent Multiscale Modelling of Three Dimensional Crack and Dislocation Propagation},
  series = {Advances in Engineering Software},
  journal   = {Advances in Engineering Software},
  pages     = {82 -- 92},
  abstract  = {Concurrent Multiscale Modelling of Three Dimensional Crack and Dislocation Propagation},
  subject      = {Angewandte Mathematik},
  language  = {en}
}
@phdthesis{Sucker,
  author    = {Sucker, Katharina},
  title     = {Communities in discourse and space. Towards a spatial dialectic in gated residential developments},
  doi       = {10.25643/bauhaus-universitaet.2346},
  url       = {http://nbn-resolving.de/urn:nbn:de:gbv:wim2-20150206-23466},
  school      = {Bauhaus-Universit{\"a}t Weimar},
  pages     = {243},
  abstract  = {This research projects deals with the discoursivity of spatial production. By looking at contemporary residential development in the city of Istanbul, I will examine the reciprocity of the material production of space on one hand, and social discourses on the other, in order to make a contribution to how physical space can be used as a source of research in urban studies. In real estate marketing social discourses are used as a source of reference for place branding or identity design. Branding concepts therefore relate to how social groups imagine their position or future position in society, imaginaries that are continuously influenced and changed by social dynamics within the city but also from the outside. How such urban identities are formed and it what way they relate to the urban environment is crucial to a wide spectrum of social and cultural science. The constitutive role urban space attains has been described and analysed in much detail. Such scrutiny however has yet to be applied to the visual and communicative forms of engagement, the build environment partakes in the formation and change of social discourses.},
  subject      = {Architektur},
  language  = {en}
}
@inproceedings{StokmaierClassSchulenbergetal.,
  author    = {Stokmaier, Markus and Class, A.G. and Schulenberg, T. and Lahey Jr., R.T},
  title     = {OPTIMISING ACOUSTIC RESONATORS FOR SONOFUSION EXPERIMENTS WITH EVOLUTIONARY ALGORITHMS},
  series = {Digital Proceedings, International Conference on the Applications of Computer Science and Mathematics in Architecture and Civil Engineering : July 20 - 22 2015, Bauhaus-University Weimar},
  booktitle = {Digital Proceedings, International Conference on the Applications of Computer Science and Mathematics in Architecture and Civil Engineering : July 20 - 22 2015, Bauhaus-University Weimar},
  editor    = {G{\"u}rlebeck, Klaus and Lahmer, Tom},
  organization    = {Bauhaus-Universit{\"a}t Weimar},
  issn      = {1611-4086},
  doi       = {10.25643/bauhaus-universitaet.2820},
  url       = {http://nbn-resolving.de/urn:nbn:de:gbv:wim2-20170314-28202},
  pages     = {8},
  abstract  = {The sizing of simple resonators like guitar strings or laser mirrors is directly connected to the wavelength and represents no complex optimisation problem. This is not the case with liquid-filled acoustic resonators of non-trivial geometries, where several masses and stiffnesses of the structure and the fluid have to fit together. This creates a scenario of many competing and interacting resonances varying in relative strength and frequency when design parameters change. Hence, the resonator design involves a parameter-tuning problem with many local optima. As its solution evolutionary algorithms (EA) coupled to a forced-harmonic FE simulation are presented. A new hybrid EA is proposed and compared to two state-of-theart EAs based on selected test problems. The motivating background is the search for better resonators suitable for sonofusion experiments where extreme states of matter are sought in collapsing cavitation bubbles.},
  subject      = {Angewandte Informatik},
  language  = {en}
}
@phdthesis{Sowoidnich,
  author    = {Sowoidnich, Thomas},
  title     = {A Study of Retarding Effects on Cement and Tricalcium Silicate Hydration induced by Superplasticizers},
  isbn      = {978-3-00-052204-8},
  doi       = {10.25643/bauhaus-universitaet.2544},
  url       = {http://nbn-resolving.de/urn:nbn:de:gbv:wim2-20160224-25444},
  school      = {Bauhaus-Universit{\"a}t Weimar},
  pages     = {214},
  abstract  = {Fließmittel werden in Betonen verwendet, um deren Fließeigenschaften w{\"a}hrend der Verarbeitung zu verbessern und Wasser einzusparen. Beide Faktoren beeinflussen nicht nur den Frischbeton, sondern auch signifikant die Festbetoneigenschaften. Nachteilig wirken sich Fließmittel auf die Festigkeitsentwicklung aus, die z.T. sehr stark verz{\"o}gert wird. Dies ist vor allem bei Bauteilen, die im Rahmen eines Vorfertigungsprozesses hergestellt werden, ein {\"o}konomischer Nachteil. Die vorliegende Arbeit widmet sich den Ursachen f{\"u}r die Verz{\"o}gerung der Portlandzementhydratation bei Verwendung von Fließmitteln. Um die komplexen Reaktionen, die w{\"a}hrend der Portlandzementhydratation auftreten, zu vereinfachen, betrachtet ein {\"u}berwiegender Teil der Arbeit die Wechselwirkung Fließmittel-Tricalciumsilikat (Abk. Ca3SiO5 oder C3S, Hauptbestandteil von Portlandzementklinker). Die Untersuchungen werden in drei Hauptteilen durchgef{\"u}hrt, wobei Methoden wie u.a. isotherme W{\"a}rmeflusskalorimetrie, Elektrische Leitf{\"a}higkeit, Elektronenmikroskopie, ICP-OES, TOC als auch Analytische Ultrazentrifugation Anwendung finden. Basierend auf der Wechselwirkung von Kationen mit anionischen Ladungstr{\"a}gern von Polymeren wird die Interaktion von Calcium mit Fließmitteln im ersten Teil der Arbeit untersucht. Dabei kommt es {\"u}berwiegend zur Komplexierung von Calciumionen durch die funktionellen Gruppen der Plymere (Carboxyl- bzw. Sulfonguppen), die in zement{\"a}ren Umgebungen sowohl gel{\"o}st in der w{\"a}ssrigen Phase als auch als Bestandteil von Partikelgrenzfl{\"a}chen vorhanden sind. Neben diesen Effekten kann auch gezeigt werden, dass Fließmittel die Bildung von nanoskaligen Partikeln hervorrufen, die infolge der sterischen Wirkung von Fließmitteln dispergiert in der w{\"a}ssrigen Phase vorliegen (Clusterbildung). Analog zu neuesten Erkenntnissen aus dem Bereich der Biomineralisation ist daher davon auszugehen, dass diese Nanopartikel durch Agglomeration das Kristallwachtsum beeinflussen. Ausgehend von der Annahme, dass die Aufl{\"o}sungs- und/ oder F{\"a}llungskinetik durch die Wirkung von Fließmitteln behindert und damit f{\"u}r den Verz{\"o}gerungseffekt der Fließmittel w{\"a}hrend der komplexen Hydratationsreaktion verantwortlich seien k{\"o}nnen, werden die zugrundeliegenden Vorg{\"a}nge im zweiten Abschnitt getrennt voneinander untersucht. Es wird anhand von L{\"o}sungsuntersuchungen an C-S-H Phasen und Portlandit herausgestellt, dass die Komplexierung von gel{\"o}sten Calciumionen durch funktionelle Gruppen der Polymere die L{\"o}slichkeit von Portlandit erh{\"o}ht. Im Gegensatz f{\"u}hrt die Komplexierung von Calciumionen in der w{\"a}ssrigen Phase zu einer Verringerung der Calciumionenkonzentration in der w{\"a}ssrigen Phase. Diese Effekte werden auf die unterschiedlich starke Adsorptionsneigung der Polymere an C-S-H-Phasen und Portlandit zur{\"u}ckgef{\"u}hrt. Es wird davon ausgegangen, dass die Adsorption aufgrund der gr{\"o}ßeren spezifischen Oberfl{\"a}che st{\"a}rker an den C-S-H-Phasen als am Portlandit auftritt. Demnach stellt sich dar, dass die Polymere erst nachdem die funktionellen Gruppen Calciumionen aus der w{\"a}ssrigen Phase komplexiert haben an den C-S-H-Phasen adsorbieren. Weiterhin kann gezeigt werden, dass die freie C3S Aufl{\"o}sungsrate in Anwesenheit von Fließmitteln keinen direkten Zusammenhang zur Verz{\"o}gerung erkennen l{\"a}sst. Teilweise kommt es zu einer in Bezug zur Kontrollprobe ohne Fließmittel erh{\"o}hten sowie auch verringerten Aufl{\"o}sungsrate. Wird das Komplexierungsvem{\"o}gen der Fließmittel ber{\"u}cksichtigt, so kann durchaus eine verlangsamte freie Aufl{\"o}sungsrate ermittelt werden. Doch auch Calcit zeigt einen verz{\"o}gernden Einfluss auf die freie C3S Aufl{\"o}sung, obwohl es den Gesamtprozess der Hydratation signifikant beschleunigt. Somit kann die behinderte Aufl{\"o}sung als m{\"o}gliche Ursache f{\"u}r die verz{\"o}gernde Wirkung w{\"a}hrend der Zementhydratation weder best{\"a}tigt noch widerlegt werden. Dieser Punkt sollte in zuk{\"u}nftigen Arbeiten weiter untersucht werden. Im letzten Schritt dieses Untersuchungsabschnitts wird die reine Kristallisation von C-S-H-Phasen und Portlandit untersucht. Es stellt sich heraus, dass Fließmittel insbesondere durch die Wirkung der Komplexierung von Ionen in der w{\"a}ssrigen Phase sowohl die Induktionszeit verl{\"a}ngern als auch die Kristallwachstumsrate ver{\"a}ndern. Dies allein kann aber nicht die komplette Verz{\"o}gerungswirkung erkl{\"a}ren. Ein wichtiger Verz{\"o}gerungsfaktor ist die Adsorption der Polymere an Kristalloberfl{\"a}chen als auch eine fließmittelbedingte Dispergierung von nanoskaligen Einzelpartikeln, die deren Agglomeration zu Kristallen behindert. Im letzten Hauptuntersuchungsabschnitt werden die gewonnenen Erkenntnisse auf die w{\"a}hrend der Zement- und Tricalciumsilikathydratation parallel ablaufenden Reaktionen analysiert. Dabei wird insbesondere die ionische Zusammensetzung der w{\"a}ssrigen Phase von C3S Pasten und Suspensionen untersucht, um Hinweise f{\"u}r eine kinetische Hemmung der Hydratationsreaktion zu identifizieren. Zusammenfassend wird festgestellt, dass die Ursachen der verz{\"o}gernden Wirkung von Fließmitteln auf die Hydratation von C3S auf die starke Verz{\"o}gerung der Kristallisation von Hydratphasen zur{\"u}ckzuf{\"u}hren ist. Dabei kommt den zwei Faktoren Komplexierung von Calciumionen an Oberfl{\"a}chen und Stabilisierung von nanoskaligen Partikeln eine zentrale Bedeutung zu. Diese Effekte k{\"o}nnen durch die Wirkung als Templat als auch durch Erh{\"o}hung der L{\"o}slichkeit infolge Komplexierung freier/gel{\"o}ster Ionen teilkompensiert werden. Dass die Aufl{\"o}sungsreaktion durch die Anwesenheit von Fließmitteln behindert wird, kann nur indirekt anhand der Entwicklung von Ionenkonzentrationen festgestellt werden. Ob dieser Vorgang die Ursache oder die Folge des L{\"o}sungs-F{\"a}llungs-Mechanismus der Hydratation ist und damit die verz{\"o}gernde Wirkung durch behinderte Aufl{\"o}sung des Edukts hervorgerufen wird, bleibt Gegenstand weiterer Untersuchungen. Im Rahmen der Arbeit kann auch gezeigt werden, dass Fließmittel chemisch als Inhibitoren wirken indem sie den Frequenzfaktor verringern. Dar{\"u}ber hinaus wird erstmalig eine Methode entwickelt, die die Bestimmung der Ionenkonzentration in Pasten in-situ erlaubt. Mit deren Hilfe wird dargestellt, dass die Entwicklung der Ionenkonzentration als auch die allgemein verwendete W{\"a}rmefreisetzungsrate (Kalorimetrie) miteinander korrespondiert. Dar{\"u}ber hinaus erlaubt die entwickelte Methode die weitere Differenzierung der Accelerationsperiode in drei Stadien. Die Kristallisation von C-S-H-Phasen und Portlandit ist f{\"u}r den Beginn der Haupthydratationsperiode entscheidend.},
  subject      = {Cement},
  language  = {en}
}